N-[2-(9-anthrylmethylamino)phenyl]-4-methylbenzenesulfonamide | 1237726-99-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-[2-(9-anthrylmethylamino)phenyl]-4-methylbenzenesulfonamide
• 英文别名: N-[2-(9-anthrylmethylamino)phenyl]-4-methyl-benzenesulfonamide；N-[2-(anthracen-9-ylmethylamino)phenyl]-4-methylbenzenesulfonamide
• CAS: 1237726-99-6
• 化学式: C₂₈H₂₄N₂O₂S
• 分子量: 452.577
• InChiKey: YPVBOUNQVOWVQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  66.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N-[2-(9-anthrylmethyleneamino)phenyl]-4-methylbenzenesulfonamide 在 sodium tetrahydroborate 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以89%的产率得到N-[2-(9-anthrylmethylamino)phenyl]-4-methylbenzenesulfonamide
  参考文献：
  名称：

  Chemosensors based on N-(2-aminophenyl)-N-(9-anthrylmethyl)amine: II

  摘要：

  A series of N-(9-anthrylmethyl)arylimines was prepared by condensation of N-(2-aminophenyl)-N-(9-anthrylmethyl)amine with aromatic aldehydes. The study of the luminescent and complexing properties of compounds obtained showed that 2-{[2-(9-anthrylmethylamino)phenylimino]methyl}-1-naphthol and 1-{[2-(9- anthrylmethylamino)phenylimino]methyl}-6-bromo-2-naphthol were efficient highly selective chemosensors of cations Hg(2+).

  DOI：

  10.1134/s1070428009020018

文献信息

• Chemosensors based on N-(2-aminophenyl)-N-(9-anthrylmethyl)amine: II
  作者：I. E. Tolpygin、E. N. Shepelenko、Yu. V. Revinskii、A. V. Tsukanov、A. D. Dubonosov、V. A. Bren’、V. I. Minkin

  DOI：10.1134/s1070428009020018

  日期：2009.2

  A series of N-(9-anthrylmethyl)arylimines was prepared by condensation of N-(2-aminophenyl)-N-(9-anthrylmethyl)amine with aromatic aldehydes. The study of the luminescent and complexing properties of compounds obtained showed that 2-[2-(9-anthrylmethylamino)phenylimino]methyl}-1-naphthol and 1-[2-(9- anthrylmethylamino)phenylimino]methyl}-6-bromo-2-naphthol were efficient highly selective chemosensors of cations Hg(2+).