[Ru(η(6)-isodurene)(μ-Cl)Cl]2 | 176207-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(η(6)-isodurene)(μ-Cl)Cl]2
• 英文别名: [(η(6)-1,2,3,5-Me4C6H2)RuCl2]2；bis[dichloro(η6-1,2,3,5-Me4C6H2)ruthenium(II)]；[RuCl2(η6-1,2,3,5-tetramethylbenzene)]2；[(1,2,3,5-Me4C6H2)RuCl2]2；dichlororuthenium;1,2,3,5-tetramethylbenzene
• CAS: 176207-50-4
• 化学式: C₂₀H₂₈Cl₄Ru₂
• 分子量: 612.394
• InChiKey: MEFTVOPCIKVHTK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(η(6)-isodurene)(μ-Cl)Cl]2 、 trans-4-isocyanoazobenzene 以 二氯甲烷 为溶剂， 以68%的产率得到[(η6-1,2,3,5-Me4C6H2)RuCl2(CNC6H4N=NC6H5)]
  参考文献：
  名称：

  带有偶氮基团的异氰化物的钌（II），铑（III）和铱（III）配合物的制备和表征

  摘要：

  的[（η反应6 -arene）的RuCl 2 ] 2（1）（η 6 -arene = p -cymene（1A），1,3,5--ME 3 Ç 6 ħ 3（1B），1,2,3- -Me 3 C 6 H 3（1c）1,2,3,4-Me 4 C 6 H 2（1d），1,2,3,5-Me 4 C 6 H 2（1e）和C 6 Me 6（1f））或[Cp * MCl2 ] 2（M = Rh（2），Ir（3）; Cp * = C 5 Me 5）与4-异氰基偶氮苯（RNC）和4,4'-二异氰基偶氮苯（CN–R–NC）得到单核和双核络合物[（η 6 -arene）的Ru（CNC 6 ħ 4 NNC 6 ħ 5）氯2 ]（4A - ˚F）的[Cp * M（CNC 6 ħ 4 NNC 6 ħ 5）氯2 ]（5：M = RH; 6：M = Ir）的， [{（η 6 -arene）的RuCl2 } 2 {μ-CNC

  DOI：

  10.1016/s0022-328x(01)01189-5
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 1,2,3,5-四甲基苯 以 not given 为溶剂， 生成 [Ru(η(6)-isodurene)(μ-Cl)Cl]2
  参考文献：
  名称：

  空间效应对{（η6-芳烃）RuCl} -C，N-环金属化胺的合成的重要性

  摘要：

  摘要[（η6-芳烃）RuCl 2] 2（η6-芳烃= C 4 H 6（苯）（1）; 1-Me-4- 1 Pr-C 6 H 4（苏木）（ 2）; 1,2,4,5-Me 4 -C 6 H 2（二烯）（3）; 1,2,3,5-Me 4 -C 6 H 2（异二烯）（4）和氨基芳基-汞衍生物Hg {Q-dmba} 2（Q-dmba = 1- {C 6 H 3 -3-F-6-CH 2 NMe 2}（a）; 1- {C 6 H 3 -6-CH 2 NMe 2}（b）; 1- {C 6 H 2 -2,3-OCH 2 OCH 2 -6-CH 2 NMe 2}（c）1- {C 6 H02,4-（MeO）2 -6-CH 2 NMe 2}（b）; 1- {C 6 H 4 CH 2 NMe 2}（e）得到相应的C，N-环钌化的配合物[η6-芳烃）RuCl {Q-dmba}。通过1 H和13 C {1 H} NMR进

  DOI：

  10.1016/0020-1693(96)05030-x

文献信息

• Preparations and structures of (η6-arene)ruthenium(II) complexes bearing 1,1′-bis(diphenylphosphinomethyl)ferrocene or 1,1′-bis(diphenylphosphino)ferrocene
  作者：Jian-Fang Mai、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(98)00499-9

  日期：1998.6

  [(η6-arene)RuCl]2(μ-dpmf)(PF6)23a without containing XylNC. Reactions of 1 with 1,1′-bis(diphenylphosphino)ferrocene (dppf) formed the bridged complexes [(arene)RuCl2]2(μ-dppf)] 4, as well as the dpmf complexes. The similar reactions in the presence of NaPF6 gave the chelated complexes [(η6-arene)RuCl(dppf-P,P′)](PF6) 5. Crystal structures of 2a, 2d·2CH2Cl2, 4a·CH2Cl2 and 5b were confirmed by X-ray analyses

  双反应[二氯（η 6 -arene）钌] 1用1,1'-双[（二苯基膦基）甲基]二茂铁（DPMF）得到dPMf- P，P'桥接的配合物[（η 6 -arene）的RuCl 2 ] 2（μ- dPMf）2，其中芳烃＝（a）1,2,3,4-Me 4 C 6 H 2；（b）C 6 Me 6 ; （c）对伞花烃；（d）1,2,3,5-Me 4 C 6 H 2；（e）1,3,5-Me 3 C 6 H 3；（f）1,2,3-Me 3 C 6 H 3。的治疗2与的NaPF存在二甲苯基胩（XylNC）6产生的F-配位的络合物[（η 6 -arene）的RuCl] 2（μ -dPMf）（PF 6）2图3a不含有XylNC。的反应1与形成在桥接配合物[（芳烃）的RuCl 1,1'-双（二苯基膦基）二茂铁（DPPF）2 ] 2（μ -DPPF）] 4，以及dPMf复合体。在的NaPF的存在下，类似的反应6得到螯合配合物[（η
• Preparation and characterization of pentamethylcyclopentadienylrhodium(III) and iridium(III), and (arene)ruthenium(II) complexes of 1,8-bis(diphenylphosphinomethyl)naphthalene
  作者：Yasuhiro Yamamoto、Fumio Miyauchi

  DOI：10.1016/s0020-1693(02)00797-1

  日期：2002.5

  1,8-Bis(diphenylphosphinomethyl)naphthalene (1,8-dpmn) reacted with [(arene)RuCl2](2) (1) or [Cp*MCl2](2) (2: M = Rh; 3: M = Ir) to generate the corresponding diphosphine-bridged complexes, [(arene)RuCl2}(2)(1,8-dpmp-P,P')] (4) (arene = p-cymene (a), 1,2,3-Me3C6H3 (b), 1,2,3,4-Me4C6H2 (d), 1,2,3,5-Me4C6H2 (d), C6Me6 (e)) or [(Cp*MCl2)(2)(1,8-dpmp-P,P')] (5: M=Rh; 6: M=Ir). Homonuclear complexes [(p-cymene)RuCl2}(1,8-dpmp-P,P')(arene)RuCl2}] 7ab and 7ad bearing different arene groups were prepared by the reactions of 1a with 1b (or 1d). They existed as two isomers in solution. Reactions of 2 with I or 3 gave heteronuclear complexes [(Cp*RhCl2)(1,8-dpmp-P,P') (arene)RuCl2}] (8) and [(Cp*RhCl2)(1,8-dpmp-P,P')(Cp*IrCl2)] (10). The heteronuclear complexes of iridium-ruthenium 9 were generated from 1 to 2. Complexes 1, 2 and 3 reacted with 1,8-dpmp in the presence of AgOTf to give the cationic complexes, [(arene)RuCl(1,8-dpmp-P,P')](OTf) (11) or [Cp*MCl(1,8-dpmp-P,P')](OTf) (12: M = Rh; 13: M = Ir) that showed the presence of isomers in solution. They were treated with Ag(OTf) to afford the Cl-bridged complexes, [(p-cymene)Ru(mu-Cl)}(2)(1,8-dpmp-P,P')](OTf)(2) (15a) or [Cp*M(mu-Cl)}(2)(1,8-dpmp-P,P')](OTf)(2) (16: M=Rh; 17: M = Ir). Complexes 16 and 17 cleaved the Cl-bridges with xylyl or mesityl isocyanide to generate the dimeric isocyanide complexes ;[Cp*MCl(RNC)}(2)(1,8-dpmp-P,P')](OTf)(2) (18: M=Rh; 19: M=Ir). X-ray analyses of 5, 8b, 10, 11a, 12, 15a and 18b were performed. (C) 2002 Elsevier Science B.V. All rights reserved.
• Homo- and heteronuclear complexes based on arene ruthenium complexes bearing bis(diphenylphosphinomethyl)phenylphosphine (dpmp)
  作者：Yasuhiro Yamamoto、Yuichi Sinozuka、Yoshihiro Tsutsumi、Kei Fuse、Katsuaki Kuge、Yusuke Sunada、Kazuyuki Tatsumi

  DOI：10.1016/j.ica.2003.10.018

  日期：2004.3

  Reactions of [(p-cymene)RuCl2](2) (1a) with dpmp ((Ph2PCH2)(2)PPh) in the absence or presence of KPF6 afforded the ionic complexes [(p-cymene)RuCl2}(dpmp-P-1,P-3,P-2)RuCl(p-cymene)}](X) (2a,: X=Cl; 2a(2): X=PF6). A (p-cymene)RuCl moiety constructs a 6-membered ring coordinated by two terminal P atoms of the dpmp ligand and another one binds to a central P atom of the ligand. Reactions of [(C6Me6)RuC](2)](2) (1b) with an excess of dpmp in the presence of KPF6 gave a 4-membered complex [(C6Me6)RuCl(dpmp-P-1, P-2)](PF6) (3b), chelated by a terminal and a central P atom and another terminal atom is free. Use of Ag(OTf) instead of KPF6 gave [(C6Me6)RuCl2(dpmp)Ag}(2)](OTf)(2) (5b) that the Ag atoms were coordinated by a terminal and a central P atom of each dpmp ligand. Reaction with an equivalent of dpmp in the presence of KPF6 gave [(C6Me6)RuCl}(dpmp-P-1,P-2,P-3)(C6Me6)RuCl2}](PF6) 4b. Complex has a structure that the (C6Me6)RuCl2 moiety coordinated to the free P atom of 3b. Complex 3b was treated with MCl2(cod) (M=Pd, Pt), [Pd(MesNC)(4)](PF6)(2) (MesNC=2,4,6-Me3C6H2NC) or [Pt-2(XylNC)(6)](PF6)(2) (XylNC=2,6-Me2C6H3NC), generating [(C6Me6)RuC](dpmp)}(2)MCl2](PF6)(2) (8b: M=Pd; 9b: M=Pt), [(C6Me6)RuCl(dpmp)}(2)Pt(MesNC)(2)}](PF6)(4) (10b) and [(C6Me6)RuCl(dpmp)}(2)Pt-2(XylNC)(4)}](PF6)(4) (11b), respectively. Complex 3b reacted readily with [Cp*MCl2](2) (M=Rh, Ir) or AuCl(SC4H8), affording the corresponding hetero-binuclear complexes [(C6Me6)RuCl}(dpmp-P-1,P-2;P-3)(MCl2Cp*](PF6) (6b: M = Rh; 7b: M = Ir) and [(C6Me6)RuCl}(dpmp-P-1, P-2, P-3)(AuCl)](PF6) (12b). These complexes have two chiral centers. Some complexes were separated as two diastereomers by successive recrystallization. The structures of 3b, 5b, 6b, 8b and 12b were confirmed by X-ray analyses. (C) 2003 Elsevier B.V. All rights reserved.