1,1'-di(chlorocarbonyl)biferrocene | 225501-93-9

• 分子结构分类: 有机化合物
• 英文名称: 1,1'-di(chlorocarbonyl)biferrocene
• 英文别名: 1',1'''-bis(chlorocarbonyl)biferrocene；cyclopenta-2,4-diene-1-carbonyl chloride;5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene;iron(2+)
• CAS: 225501-93-9
• 化学式: C₂₂H₁₆Cl₂Fe₂O₂
• 分子量: 494.968
• InChiKey: KJOXFFAUTRGQGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  DAB-1-(NHCOFc)4 、 1,1'-di(chlorocarbonyl)biferrocene 在 Et₃N 作用下， 以 二氯甲烷 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Synthesis and Electrochemical Anion-Sensing Properties of a Biferrocenyl-Functionalized Dendrimer

  摘要：

  The synthesis and electrochemical anion-sensing properties of a diaminobutane poly(propyleneimine) dendrimer functionalized with biferrocenyl units 2 are presented. The redox activity of the ferrocenyl centers in 2 has been characterized by cyclic voltammetry. Cyclic and square wave voltammetric investigations demonstrate that tetraferrocenyl compound 2 and the reference compound 1 show electrochemical anion-sensing action: they display a cathodic shift of the ferrocene ferrocenium redox couple with dihydrogenphosphate and hydrogensulfate anions in solution and immobilized onto electrode surfaces.

  DOI：

  10.1021/om3001185
• 作为产物：
  描述：

  草酰氯 、 1',1'''-bis(carboxilic acid)biferrocene 在 pyridine 作用下， 以 二氯甲烷 为溶剂， 以73%的产率得到1,1'-di(chlorocarbonyl)biferrocene
  参考文献：
  名称：

  Synthesis and Electrochemical Anion-Sensing Properties of a Biferrocenyl-Functionalized Dendrimer

  摘要：

  The synthesis and electrochemical anion-sensing properties of a diaminobutane poly(propyleneimine) dendrimer functionalized with biferrocenyl units 2 are presented. The redox activity of the ferrocenyl centers in 2 has been characterized by cyclic voltammetry. Cyclic and square wave voltammetric investigations demonstrate that tetraferrocenyl compound 2 and the reference compound 1 show electrochemical anion-sensing action: they display a cathodic shift of the ferrocene ferrocenium redox couple with dihydrogenphosphate and hydrogensulfate anions in solution and immobilized onto electrode surfaces.

  DOI：

  10.1021/om3001185