3-(anthracen-6-yl)propan-1-ol | 1072066-52-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 3-(anthracen-6-yl)propan-1-ol
• 英文别名: 3-Anthracen-2-ylpropan-1-ol；3-anthracen-2-ylpropan-1-ol
• CAS: 1072066-52-4
• 化学式: C₁₇H₁₆O
• 分子量: 236.313
• InChiKey: MLRSCGPOMUZBOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-(9,10-dihydroanthracen-6-yl)propan-1-ol 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 甲苯 为溶剂， 反应 0.08h， 以70%的产率得到3-(anthracen-6-yl)propan-1-ol
  参考文献：
  名称：

  Synthesis of Anthracene and Azaanthracene Fluorophores via [2+2+2] Cyclotrimerization Reactions

  摘要：

  A highly convergent [2+2+2]-cyclotrimerization approach to anthracenes and 2-azaanthracenes has been developed. It allows for the facile introduction of the anthracene moiety on alkyne and nitrile bearing molecules and the rapid construction of compound arrays. This is showcased in the assembly of a collection of fluorophores and their photochemical evaluation.

  DOI：

  10.1021/ol8019549

文献信息

• Synthesis of Anthracene and Azaanthracene Fluorophores via [2+2+2] Cyclotrimerization Reactions
  作者：Yan Zou、Douglas D. Young、Alejandra Cruz-Montanez、Alexander Deiters

  DOI：10.1021/ol8019549

  日期：2008.10.16

  A highly convergent [2+2+2]-cyclotrimerization approach to anthracenes and 2-azaanthracenes has been developed. It allows for the facile introduction of the anthracene moiety on alkyne and nitrile bearing molecules and the rapid construction of compound arrays. This is showcased in the assembly of a collection of fluorophores and their photochemical evaluation.