4-(2,5,8,11,18,21,24,27-Octaoxatricyclo[26.4.0.012,17]dotriaconta-1(32),12(17),13,15,28,30-hexaen-14-ylmethoxy)pyridine-2,6-dicarboxylic acid | 1093404-09-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-(2,5,8,11,18,21,24,27-Octaoxatricyclo[26.4.0.012,17]dotriaconta-1(32),12(17),13,15,28,30-hexaen-14-ylmethoxy)pyridine-2,6-dicarboxylic acid
• 英文别名: 4-(2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(32),12(17),13,15,28,30-hexaen-14-ylmethoxy)pyridine-2,6-dicarboxylic acid
• CAS: 1093404-09-1
• 化学式: C₃₂H₃₇NO₁₃
• 分子量: 643.645
• InChiKey: WGUOOMGLFGLRLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  46
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  171
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  diethyl 4-((6,7,9,10,12,13,20,21,23,24,26,27-dodecahydrodibenzo[b,n][1,4,7,10,13,16,19,22]octaoxacyclotetracosin-2-yl)methoxy)pyridine-2,6-dicarboxylate 在 lithium hydroxide 、 水 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以95%的产率得到4-(2,5,8,11,18,21,24,27-Octaoxatricyclo[26.4.0.012,17]dotriaconta-1(32),12(17),13,15,28,30-hexaen-14-ylmethoxy)pyridine-2,6-dicarboxylic acid
  参考文献：
  名称：

  A Reversible Luminescent Lanthanide Switch Based on a Dibenzo[24]-Crown-8−Dipicolinic Acid Conjugate

  摘要：

  A novel host molecule H(2)1 bearing a dibenzo[24]-crown-8 moiety and a dipicolinic acid group was synthesized, and its Tb3+ complex displayed a satisfactory luminescent emission. The tris[2]pseudorotaxane formed from [Tb.1(3)](3-) and ferrocene derivative 2 reveals excellent reversible luminescent lanthanide behavior.

  DOI：

  10.1021/ol802376k

文献信息

• A Reversible Luminescent Lanthanide Switch Based on a Dibenzo[24]-Crown-8−Dipicolinic Acid Conjugate
  作者：Min Han、Heng-Yi Zhang、Li-Xu Yang、Qiao Jiang、Yu Liu

  DOI：10.1021/ol802376k

  日期：2008.12.18

  A novel host molecule H(2)1 bearing a dibenzo[24]-crown-8 moiety and a dipicolinic acid group was synthesized, and its Tb3+ complex displayed a satisfactory luminescent emission. The tris[2]pseudorotaxane formed from [Tb.1(3)](3-) and ferrocene derivative 2 reveals excellent reversible luminescent lanthanide behavior.