| 111130-26-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 111130-26-8
• 化学式: C₁₈H₃₈N₂S₄Sn
• 分子量: 529.487
• InChiKey: KEZLTQZQAUMILP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.18
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper diethyldithiocarbamate 、 tris(diethyldithiocarbamato)iron(III) 、 在 (8Z)-heptadec-8-en-1-amine 作用下， 反应 1.0h， 生成
  参考文献：
  名称：

  Synthesis of Nanoparticulate Alloys of the Composition Cu₂Zn_1–xFe_xSnS₄: Structural, Optical, and Magnetic Properties

  摘要：

  Nanoparticles of the semiconductor Cu2Zn1-xFexSnS4 with different mole fractions of iron (x(Fe)) were synthesized by the decomposition of molecular precursors in oleylamine. The composition, structure, optical, and magnetic properties of the nanoparticles are reported. The parent (Cu2ZnSnS4) zinc material is usually reported as kesteritic and the corresponding iron phase as stannitic; with different site occupancies and tetragonalities. In the small ca. 8-10 nm particles prepared, the smooth variation in lattice parameters and other measured properties suggest that the phase change, with composition, may be absent. SQUID magnetometry suggests that the iron containing samples are ferromagnetic at 5 K and paramagnetic at 300 K.

  DOI：

  10.1021/jacs.5b10281
• 作为产物：
  描述：

  二丁基二氯化锡 、 sodium N,N-diethyldithiocarbamate 以 乙醇 为溶剂， 反应 0.5h， 以60%的产率得到
  参考文献：
  名称：

  有机锡二硫代氨基甲酸酯：通过气溶胶辅助化学气相沉积（AACVD）用于硫化锡薄膜的单源前体

  摘要：

  一系列的二硫代氨基甲酸盐[Sn（C 4 H 9）2（S 2 CN（RR'）2）2 ]（R，R'=乙基（1）； R =甲基，R'=丁基（2） ； R，R'=丁基（3）； R =甲基，R'=己基（4）；以及[Sn（C 6 H 5）2（S 2 CN（RR'）2）2 ]（R，R' ＝乙基（5）； R ＝甲基，R′＝丁基（6）； R，R′＝丁基（7）； R ＝甲基，R′＝己基（8））合成。的单晶X射线结构2，3，和8进行了测定。热重量分析（TGA）显示出对络合物单步分解1，3，及5 - 8，和双分解步的复合物2和4和325之间195℃℃。复杂1 – 4在400°C至530°C的温度下，它们用作通过气溶胶辅助化学气相沉积（AACVD）沉积SnS薄膜的单源前驱体。在所有沉积温度下，从所有四个络合物沉积正交晶SnS薄膜。膜的特征在于紫外可见光谱，粉末X射线衍射（p-XRD），拉曼光谱，扫描电子显微镜（SE

  DOI：

  10.1021/cm301660n

文献信息

• Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)
  作者：Karthik Ramasamy、Vladimir L. Kuznetsov、Kandasamy Gopal、Mohammad A. Malik、James Raftery、Peter P. Edwards、Paul O’Brien

  DOI：10.1021/cm301660n

  日期：2013.2.12

  between 195 °C and 325 °C. Complexes 1–4 were used as single-source precursors for the deposition of SnS thin films by aerosol-assisted chemical vapor deposition (AACVD) at temperatures from 400 °C to 530 °C. Orthorhombic SnS thin films were deposited from all four complexes at all deposition temperatures. The films were characterized by UV–vis spectroscopy, powder X-ray diffraction (p-XRD), Raman spectroscopy

  一系列的二硫代氨基甲酸盐[Sn（C 4 H 9）2（S 2 CN（RR'）2）2 ]（R，R'=乙基（1）； R =甲基，R'=丁基（2） ； R，R'=丁基（3）； R =甲基，R'=己基（4）；以及[Sn（C 6 H 5）2（S 2 CN（RR'）2）2 ]（R，R' ＝乙基（5）； R ＝甲基，R′＝丁基（6）； R，R′＝丁基（7）； R ＝甲基，R′＝己基（8））合成。的单晶X射线结构2，3，和8进行了测定。热重量分析（TGA）显示出对络合物单步分解1，3，及5 - 8，和双分解步的复合物2和4和325之间195℃℃。复杂1 – 4在400°C至530°C的温度下，它们用作通过气溶胶辅助化学气相沉积（AACVD）沉积SnS薄膜的单源前驱体。在所有沉积温度下，从所有四个络合物沉积正交晶SnS薄膜。膜的特征在于紫外可见光谱，粉末X射线衍射（p-XRD），拉曼光谱，扫描电子显微镜（SE
• Studies on the preparation and characterization of bis-dithiocarbamato derivatives of di-n-butyl- and di-n-hexyl Sn(IV)
  作者：C.P. Sharma、N. Kumar、M.C. Khandpal、S. Chandra、V.G. Bhide

  DOI：10.1016/0022-1902(81)80151-0

  日期：1981.1

  Di-alkyl tin(IV) bis-dithiocarbamato complexes of the type R2Sn(IV)[R′R″dtc]2 or R2Sn(IV)[morph. dtc]2 (where R = n-Bu, n-Hex, R′ = R″ = Me, Et, i-Pr; R′ = Me and R″ = Ph) have been prepared by the reaction of di-n-butyl or di-n-hexyl Sn(IV) dichloride with the sodium salt of respective dithiocarbamic acid in 1:2 molar ratio in dry acetone. The IR, 1H NMR and Mossbauer studies indicate an anisobidentate

  R 2 Sn（IV）[R'R''dtc] 2或R 2 Sn（IV）[晶型类型的二烷基锡（IV）双-二硫代氨基甲酸酯络合物。DTC] 2（R =其中Ñ -Bu，Ñ -六角，R'= R“=甲基，乙基，异-镨; R'=我和R”= PH）已经制备由二的反应Ñ -丁基或二正己基二氯化锡（Ⅳ）与二硫代氨基甲酸的钠盐在无水丙酮中的摩尔比为1：2。IR，1 H NMR和Mossbauer研究表明这些络合物中dtc（二硫代氨基甲酸酯）配体具有各向异性特征。
• Dakternieks, Dainis; Zhu, Hongjian; Masi, Dante, Inorganic Chemistry, 1992, vol. 31, # 17, p. 3601 - 3606
  作者：Dakternieks, Dainis、Zhu, Hongjian、Masi, Dante、Mealli, Carlo

  DOI：——

  日期：——
• Vrabel, V.; Lokaj, J.; Kelloe, E., Acta Crystallographica, Section C: Crystal Structure Communications, <hi>1992</hi>, vol. 48, p. 633 - 635
  作者：Vrabel, V.、Lokaj, J.、Kelloe, E.、Garaj, J.、Batsanov, A. C.、Struchkov, Yu. T.

  DOI：——

  日期：——
• Synthesis of Nanoparticulate Alloys of the Composition Cu₂Zn_1–<i>x</i>Fe_<i>x</i>SnS₄: Structural, Optical, and Magnetic Properties
  作者：Punarja Kevin、Mohammad Azad Malik、Simon Mcadams、Paul O’Brien

  DOI：10.1021/jacs.5b10281

  日期：2015.12.9

  Nanoparticles of the semiconductor Cu2Zn1-xFexSnS4 with different mole fractions of iron (x(Fe)) were synthesized by the decomposition of molecular precursors in oleylamine. The composition, structure, optical, and magnetic properties of the nanoparticles are reported. The parent (Cu2ZnSnS4) zinc material is usually reported as kesteritic and the corresponding iron phase as stannitic; with different site occupancies and tetragonalities. In the small ca. 8-10 nm particles prepared, the smooth variation in lattice parameters and other measured properties suggest that the phase change, with composition, may be absent. SQUID magnetometry suggests that the iron containing samples are ferromagnetic at 5 K and paramagnetic at 300 K.