2-ethyl-3-tetrahydrofurylthiol | 139331-14-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: 2-ethyl-3-tetrahydrofurylthiol
• 英文别名: 2-Ethyldihydrofuran-3-thiol；2-ethyltetrahydrofuran-3-thiol；2-Ethyloxolane-3-thiol
• CAS: 139331-14-9
• 化学式: C₆H₁₂OS
• 分子量: 132.227
• InChiKey: TVYBBVQTTVRLFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  10.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-ethyl-3-tetrahydrofuryl thiocyanate 在 甲基碘化镁 作用下， 以 乙醚 为溶剂， 反应 2.0h， 以81%的产率得到bis(2-ethyl-3-tetrahydrofuryl) disulfide
  参考文献：
  名称：

  Homolytic dissociation of the carbon-element ? bonds by Grignard reagents

  摘要：

  The reaction of 2-ethyl-3-tetrahydrofuryl thiocyanate (I) and triphenylacetonitrile (VIII) with methylmagnesium iodide in ether was studied using GC/MS, PMR and C-13 NMR spectroscopy. The reaction of (I) with CH3MgI giveS the product of the homolysis of the C-S sigma bond, namely, bis(2-ethyl-3-tetrahydrofuryl) disulfide (II), in 81% yield. This reaction is assumed to be general in nature since triphenylacetonitrile (VIII) is also homolytically cleaved by the action of CH3MgI to give triphenylmethane.

  DOI：

  10.1007/bf00959737

文献信息

• Ethyl 4-(thioacetoxy)butyrate as a flavoring agent and methods for preparing and using same
  申请人：——

  公开号：US20020090435A1

  公开（公告）日：2002-07-11

  This invention pertains to a method for flavoring an ingestible composition with a flavoring agent in organoleptically purified form, unaccompanied by substances of natural origin present in mango. The flavoring agent may be used in a wide variety of ingestible vehicles such as chewing gum compositions, hard and soft confections, dairy products, beverage products including juice drinks and juice products, green vegetable and chicken products, and the like. The present invention also pertains to an ingestible composition comprising an ingestible vehicle and an organoleptically effective amount of the purified flavoring agent. The present invention also pertains to ethyl 4-(thioacetoxy)butyrate represented by the formula, CH 3 COS(CH 2 ) 3 COOCH 2 CH 3 .

  本发明涉及一种用有机纯化形式的调味剂为可食用组合物调味的方法，该调味剂不含芒果中存在的天然物质。该调味剂可用于多种可食用载体，如口香糖组合物、软硬糖果、乳制品、饮料产品（包括果汁饮料和果汁产品）、绿色蔬菜和鸡肉产品等。本发明还涉及一种可食用组合物，该组合物由可食用载体和有机有效量的纯化调味剂组成。本发明还涉及 4-(硫代乙酰氧基)丁酸乙酯，其代表式为 CH 3 COS(CH 2 ) 3 COOCH 2 CH 3 .
• ETHYL 4-(THIOACETOXY)BUTYRATE AS A FLAVORING AGENT AND METHODS FOR PREPARING AND USING SAME
  申请人：Bush Boake Allen Inc.

  公开号：EP1276391A1

  公开（公告）日：2003-01-22
• EP1276391A4
  申请人：——

  公开号：EP1276391A4

  公开（公告）日：2005-11-09
• US3985908A
  申请人：——

  公开号：US3985908A

  公开（公告）日：1976-10-12
• US3988510A
  申请人：——

  公开号：US3988510A

  公开（公告）日：1976-10-26