(1S,2S)-(-)-N,N'-bis(3,5-dichlorosalicylidene)-trans-1,2-cyclohexane disulfonamide | 170376-86-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1S,2S)-(-)-N,N'-bis(3,5-dichlorosalicylidene)-trans-1,2-cyclohexane disulfonamide
• 英文别名: 3,5-dichloro-N-[(1S,2S)-2-[(3,5-dichloro-2-hydroxyphenyl)sulfonylamino]cyclohexyl]-2-hydroxybenzenesulfonamide
• CAS: 170376-86-0
• 化学式: C₁₈H₁₈Cl₄N₂O₆S₂
• 分子量: 564.295
• InChiKey: HJPDAEKXWUUQGK-KBPBESRZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  150
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (1S,2S)-(-)-N,N'-bis(3,5-dichlorosalicylidene)-trans-1,2-cyclohexane disulfonamide 、 manganese (II) acetate tetrahydrate 在 sodium methylate 作用下， 以 乙醇 为溶剂， 以67%的产率得到(1S,2S)-(+)-N,N'-bis(3,5-dichlorosalicylidene)-trans-1,2-cyclohexane disulfonamidomanganese(III) sodium salt
  参考文献：
  名称：

  Synthesis and characterization of manganese(III) complexes of a chiral disulfonamide ligand based on trans-1,2-diaminocyclohexane

  摘要：

  The synthesis and characterization of an optically active disulfonamide ligand based on trans-1,2-diaminocyclohexane as chiral motif is reported. The corresponding anionic manganese(III) complex has been evaluated as potential catalyst for enantioselective olefin epoxidations, and found to be inactive. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00583-9

文献信息

• Synthesis and characterization of manganese(III) complexes of a chiral disulfonamide ligand based on trans-1,2-diaminocyclohexane
  作者：Katia Bernardo、Anne Robert、Bernard Meunier

  DOI：10.1016/s0277-5387(96)00583-9

  日期：1997.1

  The synthesis and characterization of an optically active disulfonamide ligand based on trans-1,2-diaminocyclohexane as chiral motif is reported. The corresponding anionic manganese(III) complex has been evaluated as potential catalyst for enantioselective olefin epoxidations, and found to be inactive. (C) 1997 Elsevier Science Ltd.