1-(Chloromethyl)bicyclo[2.2.1]hept-2-ene | 1824221-34-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-(Chloromethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 1824221-34-2
• 化学式: C₈H₁₁Cl
• 分子量: 142.62
• InChiKey: JFMXMDVWTVJDGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-(Chloromethyl)bicyclo[2.2.1]hept-2-ene 、 二甲基亚砜 、 sodium cyanide 在 氮 、 sodium cyanide 、 水 、 甲基叔丁基醚 、 Sodium sulfate-III 作用下， 以 甲基叔丁基醚 为溶剂， -90.0~350.0 ℃ 、16.71 kPa 条件下， 反应 91.03h， 以to give 112 g (100% yield) with 95.8% purity by GC的产率得到Cyanomethylnorbornene
  参考文献：
  名称：

  INTERLAYER FOR ELECTRONIC DEVICES

  摘要：

  本发明的实施例提供了在电子设备中使用多环氧烷烃的方法，更具体地，是将这种多环氧烷烃用作在制造电子设备时应用于氟聚合物层的中间层，包括这种多环氧烷烃中间层的电子设备以及制备这种多环氧烷烃中间层和电子设备的方法。

  公开号：

  US20120056249A1

文献信息

• Metal complexes useful in metathesis and other reactions
  申请人：Walter Francis

  公开号：US20050043541A1

  公开（公告）日：2005-02-24

  This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

  本发明提供了金属配合物，可用作交换反应中的催化剂组分，以及涉及将原子或基团转移至乙烯基或乙炔基不饱和化合物或其他反应底物的反应中，并且针对其亚类别，用于α-烯烃和可选的共轭二烯的聚合，具有在中等温度下高活性。它还提供了通过活性反应获得非常窄的分子量分布的聚合物的方法。它还提供了制备该金属配合物和涉及这种方法的新型中间体的方法。它还提供了该金属配合物的衍生物，适用于与载体进行共价键合，该共价键合的产物可用作异相催化反应的支持催化剂。它还提供了从双烯基化合物直接合成吡咯、呋喃和噻吩化合物的一步法。
• GATE INSULATOR LAYER FOR ORGANIC ELECTRONIC DEVICES
  申请人：Mueller David Christoph

  公开号：US20120056183A1

  公开（公告）日：2012-03-08

  Embodiments in accordance with the present invention provide for the use of polycycloolefins in electronic devices and more specifically to the use of such polycycloolefins as gate insulator layers used in the fabrication of electronic devices, the electronic devices that encompass such polycycloolefin gate insulator and processes for preparing such polycycloolefin gate insulator layers and electronic devices encompassing such layers.

  本发明实施例提供了在电子设备中使用多环烯烃的方法，更具体地，提供了使用此类多环烯烃作为电子设备制造中用于制造栅绝缘层的栅绝缘层的方法，以及包括此类多环烯烃栅绝缘层的电子设备和制备此类多环烯烃栅绝缘层和包括此类层的电子设备的工艺。
• Co-polymer-bound amine antioxidants
  申请人：HERCULES INCORPORATED

  公开号：EP0331074A2

  公开（公告）日：1989-09-06

  An improved amine-containing antioxidant compound for stabilizing the polymeric products of ring-opening metathesis-catalyst-polymerization of the norbornene-type monomer reactions described above, and that effectively delays degradation by olefin oxidation of physical properties as well as avoiding discoloration of such polymeric products and discoloration of surface coatings applied for aesthetic purposes, and its use as a comonomer in a ring-opening metathesis-catalyst-polymerization of a norbornene-type monomer that undergoes ring-opening polymerization in the presence of a metathesis catalyst are disclosed.

  一种改进的含胺抗氧化剂化合物，用于稳定上述降冰片烯类单体反应的开环偏聚催化剂聚合反应的聚合物产物，并能有效延缓物理性能因烯烃氧化而降解，以及避免此类聚合物产物变色和为美观目的而使用的表面涂层变色、本发明还公开了其在降冰片烯类单体的开环偏合成催化剂聚合反应中作为共聚单体的用途，该单体在偏合成催化剂存在下进行开环聚合反应。
• Metal carbene complexes, methods and intermediates for making them and their use in metathesis reactions
  申请人：UNIVERSITEIT GENT

  公开号：EP1329455A1

  公开（公告）日：2003-07-23

  Compounds having one of the general formulae:    wherein: M is a metal; Z is selected from the group consisting of oxygen, sulphur, NR"" and PR""; R", R"' and R"" are each a radical independently selected from hydrogen, C1-6 alkyl, C3-8 cycloalkyl, aryl and heteroaryl, or R" and R"' together form an aryl or heteroaryl radical, each said radical being optionally substituted; R' is either as defined for R", R"' and R"" when included in a compound having the general formula (IA) or, when included in a compound having the general formula (IB), is selected from hydrogen, C1-6 alkylene and C3-8 cycloalkylene, the said alkylene and cycloalkylene group being optionally substituted; R1 is a constraint steric hindrance group having a pKa of at least about 15; R2 is an anionic ligand; R3 and R4 are each hydrogen or a radical selected from, among others, C1-20 alkyl, C1-20 alkenyl; R3 and R4 together may form a fused aromatic ring system, and y represents the number of sp2 carbon atoms between M and the carbon atom bearing R3 and R4 and is an integer from 0 to 3 inclusive are useful as catalysts for olefin metathesis and atom transfer radical polymerization.

  具有下列通式之一的化合物 其中 M 是金属； Z 选自由氧、硫、NR""和 PR""组成的组； R"、R"'和 R""各自是独立选自氢、C1-6 烷基、C3-8 环烷基、芳基和杂芳基的基团，或 R" 和 R"'共同形成芳基或杂芳基，每个所述基团均被任选取代； 当包含在通式（IA）化合物中时，R'与 R"、R"'和 R""的定义相同；当包含在通式（IB）化合物中时，R'选自氢、C1-6 亚烷基和 C3-8 环亚烷基，所述亚烷基和环亚烷基任选被取代； R1 是一个限制性立体阻碍基团，其 pKa 至少约为 15； R2 是阴离子配体； R3 和 R4 分别为氢或选自 C1-20 烷基、C1-20 烯基等的自由基； R3 和 R4 可共同形成一个融合的芳香环系统，以及 y 代表 M 与含有 R3 和 R4 的碳原子之间的 sp2 碳原子数，是 0 至 3（包括 3 个）的整数。 可用作烯烃偏聚和原子转移自由基聚合的催化剂。
• Metal complexes for use in metathesis, atom transfer radical reactions, addition polymerisation and vinylation reactions, methods and intermediates for making them
  申请人：UNIVERSITEIT GENT

  公开号：EP1743899A1

  公开（公告）日：2007-01-17

  This invention relates to metal complexes which are useful as catalyst components in olefin metathesis reactions, atom or group transfer radical polymerisation or addition reactions and vinylation reactions. It also relates to the direct one-step synthesis of pyrrole, furan and thiophene compounds, such as dialkyl 1H-pyrrol-1-yl methyl phosphonates, from diallyl compounds.

  本发明涉及在烯烃偏聚反应、原子或基团转移自由基聚合或加成反应以及乙烯基化反应中用作催化剂组分的金属络合物。本发明还涉及从二烯丙基化合物中一步直接合成吡咯、呋喃和噻吩化合物，如 1H-吡咯-1-基甲基膦酸二烷基酯。