[(Z)-1-chloro-2-[4-[(Z)-2-chloro-2-trimethylsilylethenyl]phenyl]ethenyl]-trimethylsilane | 1163150-78-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(Z)-1-chloro-2-[4-[(Z)-2-chloro-2-trimethylsilylethenyl]phenyl]ethenyl]-trimethylsilane
• CAS: 1163150-78-4
• 化学式: C₁₆H₂₄Cl₂Si₂
• 分子量: 343.444
• InChiKey: IKTWJUSZMQWRAZ-JOBJLJCHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  C₂₂H₄₂O₂Si₄ 在 盐酸 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 24.0h， 生成 、 [(Z)-1-chloro-2-[4-[(Z)-2-chloro-2-trimethylsilylethenyl]phenyl]ethenyl]-trimethylsilane
  参考文献：
  名称：

  1,4-bis[2,2-bis(trimethylsilyl)ethenyl]benzene: Regioselective ring opening of its α,β-epoxybis(silane) with some nucleophiles

  摘要：

  The Peterson olefination reaction of terephthalaldehyde with tris(trimethylsilyl) methyllithium, (Me3Si)(3)-CLi, in Et2O gives disubstituted vinylbis(silane) 1 which reacts with MCPBA in CH2Cl2 at r.t. to afford mixture of mono and disubstituted epoxybis(silanes) 3 and 2. Vinylbis(silane) 1 can be completely converted into epoxybis(silane) 2 with an excess amount of MCPBA. The compound 2 was reacted with various reagents such as HX (X = Cl, Br), H2SO4, LiAlH4 and MeLi/CuI and give the related products. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.01.030

文献信息

• 1,4-bis[2,2-bis(trimethylsilyl)ethenyl]benzene: Regioselective ring opening of its α,β-epoxybis(silane) with some nucleophiles
  作者：Kazem D. Safa、Khatereh Ghorbanpour、Akbar Hassanpour、Shahin Tofangdarzadeh

  DOI：10.1016/j.jorganchem.2009.01.030

  日期：2009.5

  The Peterson olefination reaction of terephthalaldehyde with tris(trimethylsilyl) methyllithium, (Me3Si)(3)-CLi, in Et2O gives disubstituted vinylbis(silane) 1 which reacts with MCPBA in CH2Cl2 at r.t. to afford mixture of mono and disubstituted epoxybis(silanes) 3 and 2. Vinylbis(silane) 1 can be completely converted into epoxybis(silane) 2 with an excess amount of MCPBA. The compound 2 was reacted with various reagents such as HX (X = Cl, Br), H2SO4, LiAlH4 and MeLi/CuI and give the related products. (C) 2009 Elsevier B.V. All rights reserved.