5-(cyclohexen-3-yl)bicyclo[2.2.1]pent-2-ene | 10433-27-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: 5-(cyclohexen-3-yl)bicyclo[2.2.1]pent-2-ene
• 英文别名: 5-(Cyclohexen-3-yl)bicyclo[2.2.1]hept-2-ene；5-cyclohex-2-en-1-ylbicyclo[2.2.1]hept-2-ene
• CAS: 10433-27-9
• 化学式: C₁₃H₁₈
• 分子量: 174.286
• InChiKey: YAJJLYZQHRJWJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-(cyclohexen-3-yl)bicyclo[2.2.1]pent-2-ene 在 双氧水 、 溶剂黄146 作用下， 以 水 为溶剂， 反应 4.0h， 生成 exo-6-(cyclohex-3-enyl)-exo-3-oxatricyclo[3.2.1.0^2.4]octane 、 exo-5-(cycloxex-3-enyl)bicyclo[2.2.1]heptan-exo,endo-2,3-diol
  参考文献：
  名称：

  Oxidative dihydroxylation of alicyclic unsaturated hydrocarbons with vinyl- and norbornene fragments in pseudohomogenic system

  摘要：

  Oxidation of alicyclic unsaturated hydrocarbons (4-vinylcyclohexene, 5-vinylnorbornene, 5-cyclohexenylnorbornene, and 5-vinylbicyclooctene) with 30% hydrogen peroxide solutions and percarbamide is studied. Reaction was carried out at 40-70A degrees C in the presence of heterogenized peroxocomplex compounds of molybdenum and tungsten formed "in situ" in the reaction of metal oxohalides with H3PO4, nano-dimensional particles of carbon material, and hydrogen peroxide. Main oxidation products of alicyclic diene hydro-carbons are the corresponding unsaturated epoxides and diols. Depending on the reaction condition their ratio varies in a wide range.

  DOI：

  10.1134/s1070363213010118