2-(1-Phenylphosphindol-2-yl)thiophene | 1034024-49-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(1-Phenylphosphindol-2-yl)thiophene
• 英文别名: 2-(1-phenylphosphindol-2-yl)thiophene
• CAS: 1034024-49-1
• 化学式: C₁₈H₁₃PS
• 分子量: 292.341
• InChiKey: REUSEQMDPCOBQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  C₁₈H₁₃OPS 在 三氯硅烷 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以78%的产率得到2-(1-Phenylphosphindol-2-yl)thiophene
  参考文献：
  名称：

  Base-Mediated Cyclization Reaction of 2-Alkynylphenylphosphine Oxides: Synthesis and Photophysical Properties of Benzo[b]phosphole Oxides

  摘要：

  The base-mediated intramolecular cyclization reaction of 2-alkynylphenylphosphine oxides affords benzo[b]phosphole oxides, which show intense blue-green fluorescence. Benzo[b]phospholes are also prepared by the reduction of benzo[b]phosphole oxides.

  DOI：

  10.1021/ol800841v

文献信息

• Base-Mediated Cyclization Reaction of 2-Alkynylphenylphosphine Oxides: Synthesis and Photophysical Properties of Benzo[<i>b</i>]phosphole Oxides
  作者：Takanobu Sanji、Kentaro Shiraishi、Taigo Kashiwabara、Masato Tanaka

  DOI：10.1021/ol800841v

  日期：2008.7.3

  The base-mediated intramolecular cyclization reaction of 2-alkynylphenylphosphine oxides affords benzo[b]phosphole oxides, which show intense blue-green fluorescence. Benzo[b]phospholes are also prepared by the reduction of benzo[b]phosphole oxides.