{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II) | 33971-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)
• 英文别名: Pd(C6H5S)2(1,2-bis(diphenylphosphanyl)ethane)；(SC6H5)2[1,2-bis(diphenylphosphanyl)ethane]palladium；palladium(SPh)2(1,2-bis(diphenylphosphino)ethane)
• CAS: 33971-07-2
• 化学式: C₃₈H₃₄P₂PdS₂
• 分子量: 723.187
• InChiKey: BPAAMZLWSIMYHZ-UHFFFAOYSA-L

物化性质

• 熔点：
  208-212 °C

计算性质

• 辛醇/水分配系数(LogP)：
  9.74
• 重原子数：
  43.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  {1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II) 在 盐酸 作用下， 以 not given 为溶剂， 生成 1,2-二(二苯基膦基)乙烷二氯化钯(II)
  参考文献：
  名称：

  Xu, Chongfu; Siria, Jeffrey W.; Anderson, Gordon K., Inorganica Chimica Acta, 1993, vol. 206, p. 123 - 126

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二(二苯基膦基)乙烷二氯化钯(II) 、 bis(benzenethiolato)lead(II) 以 丙酮 为溶剂， 以66%的产率得到{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)
  参考文献：
  名称：

  Synthesis and characterisation of mono- and binuclear palladium and platinum complexes with organochalcogenides

  摘要：

  Mononuclear palladium and platinum complexes of the type M(ER)(2)((PP)-P-boolean AND) [M = Pd or Pt; ER = SPh, SC6H4Cl-4, SC6H4Me-4, SC6F5, SePh, TeC6H4OEt-4; (PP)-P-boolean AND = dppm or dppe] have been prepared and their ability to form dinuclear metal species has been demonstrated. All complexes have been characterised by multinuclear magnetic resonance (H-1, C-13, Se-77, Pt-195) spectral data. The effects of phosphine ligands and organochalcogenides are reflected in the Se-77 and Pt-195 NMR shifts. The shielding of Pt-195 NMR chemical shifts has been interpreted in terms of their binding ability to platinum. The structures of two derivatives, namely [Pd(SC6F5)(2)(dppe)] and [Pd(SePh)(2)(dppe)], have been established by X-ray crystallography. The palladium atom in each of the monomeric structures exists in a square planar geometry. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00335-1

文献信息

• The Insertion of Dimethyl Acetylenedicarboxylate into an S-Pd Bond
  作者：Kunihiko Sugoh、Hitoshi Kuniyasu、Hideo Kurosawa

  DOI：10.1246/cl.2002.106

  日期：2002.1

  The first definitive evidence of insertion of an alkyne into an S-Pd bond has been presented. The reaction of Pd(SAr)2(DPPE) with dimethyl acetylenedicarboxylate (DMAD) gave the cis-insertion product (Z)-Pd-[C(CO2Me)=C(SAr)(CO2Me)](SAr)(DPPE), whose structure was unambiguously determined by X-ray crystallographic analysis.

  已经提出了炔烃插入 S-Pd 键的第一个明确证据。Pd(SAr)2(DPPE)与乙炔二羧酸二甲酯(DMAD)反应得到顺式插入产物(Z)-Pd-[C(CO2Me)=C(SAr)(CO2Me)](SAr)(DPPE)，其结构由 X 射线晶体学分析明确确定。
• Roundhill, D. Max, Inorganic Chemistry, 1980, vol. 19, # 2, p. 557 - 560
  作者：Roundhill, D. Max

  DOI：——

  日期：——
• (Phenylalkyl)palladium Complexes Containing β-Hydrogen Atoms: Synthesis and Characterization of [PdR2(dppe)], [PdR(SPh)(dppe)] (R = CH2CH2Ph, CH2CH2CH2Ph, CH2CHMePh), and [Pd(CH2CH2CH2Ph)X(dppe)] (X = I, Br, Cl)
  作者：Thomas Spaniel、Harry Schmidt、Christoph Wagner、Kurt Merzweiler、Dirk Steinborn

  DOI：10.1002/1099-0682(200211)2002:11<2868::aid-ejic2868>3.0.co;2-s

  日期：2002.11
• Synthesis of Homo- and Hetero-Bimetallic Complexes Containing the Ni(C6F5)2 Moiety – Crystal Structure of [(C6F5)2Ni(μ-SPh)2Pd(dppe)]
  作者：Gregorio Sánchez、Francisca Momblona、Mateo Sánchez、José Pérez、Gregorio López、Jaume Casabó、Elies Molins、Carles Miravitlles

  DOI：10.1002/(sici)1099-0682(199808)1998:8<1199::aid-ejic1199>3.0.co;2-k

  日期：1998.8
• Synthesis and characterization of heterodinuclear thiolate complexes containing the Pd(η3-allyl)+ moiety. Crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4]
  作者：José Ruiz、José Giner、Venancio Rodrı́guez、Gregorio López、Jaume Casabó、Elies Molins、Carles Miravitlles

  DOI：10.1016/s0277-5387(00)00440-x

  日期：2000.7

  Hetero dinuclear complexes of the types [(dppe)M(mu-SR)(2)Pd(eta(3)-allyl)][ClO4] (M = Pd or Pt) and [(dppe)Pt(mu-SC2H4S)Pd(eta(3)-allyl)][ClO4] [dppe = 1,2-bis(diphenylphosphino)ethane; allyl = C3H5 or C4H7] have been obtained by reaction of the corresponding cis-dithiolato complexes, [M(SR)(2) (dppe)] or [Pt(SC2H4S)(dppe)]. and [Pd(eta(3)-allyl)(PhCN)(2)][ClO4]. The identity of these complexes has been established by NMR (H-1 and P-31) spectroscopy. The crystal structure of [(dppe)Pd(mu-SC6H4Me-p)(2)Pd(eta(3)-C3H5)][ClO4] has been determined by single-crystal X-ray methods. The p-tolyl groups on the sulfur atoms adopt a syn conformation with respect to the central Pd-S-2-Pd core. (C) 2000 Elsevier Science Ltd. All rights reserved.