Sodium;4-(3,5-dibromo-2-oxopyridin-1-yl)butane-1-sulfonate | 1415551-35-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Sodium;4-(3,5-dibromo-2-oxopyridin-1-yl)butane-1-sulfonate
• 英文别名: sodium;4-(3,5-dibromo-2-oxopyridin-1-yl)butane-1-sulfonate
• CAS: 1415551-35-7
• 化学式: C₉H₁₀Br₂NO₄S*Na
• 分子量: 411.046
• InChiKey: CLABFPBRNIHPRA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  85.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-丁磺酸内酯 、 3,5-二溴-2-羟基嘧啶 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 24.0h， 以47%的产率得到Sodium;4-(3,5-dibromo-2-oxopyridin-1-yl)butane-1-sulfonate
  参考文献：
  名称：

  Preparation of poly(2-pyridone-3,5-diyl)s with –(CH2)4–SO3M (M = H or Na) side chains

  摘要：

  Poly(2-pyridone-3,5-diyl)s with -(CH2)(4)-SO3M (M = H or Na) side chains have been prepared by nickel-complex promoted dehalogenative polycondensation. A composite film of the polymer with -(CH2)(4)-SO3H side chains and poly(vinyl alcohol) showed a proton conductivity of 1.5 x 10(-1) S cm(-1) at 80 degrees C and 95% humidity. A copolymer with pyridine showed a high stability against oxidation by a Fenton reagent. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2012.09.032

文献信息

• Preparation of poly(2-pyridone-3,5-diyl)s with –(CH2)4–SO3M (M = H or Na) side chains
  作者：Takakazu Yamamoto、Tohru Takei、Naoto Kumagai、Yosuke Harada、Takumi Ohki、Yasuo Kudoh、Takahiro Kojima、Take-aki Koizumi、Kohei Shiramizu、Masahiro Abe、Masashi Oota

  DOI：10.1016/j.polymer.2012.09.032

  日期：2012.12

  Poly(2-pyridone-3,5-diyl)s with -(CH2)(4)-SO3M (M = H or Na) side chains have been prepared by nickel-complex promoted dehalogenative polycondensation. A composite film of the polymer with -(CH2)(4)-SO3H side chains and poly(vinyl alcohol) showed a proton conductivity of 1.5 x 10(-1) S cm(-1) at 80 degrees C and 95% humidity. A copolymer with pyridine showed a high stability against oxidation by a Fenton reagent. (C) 2012 Elsevier Ltd. All rights reserved.