| 210549-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 210549-23-8
• 化学式: C₁₈H₂₀F₃NPtS
• 分子量: 534.505
• InChiKey: ILCCLGUAYMGADR-BHNFNVEASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三苯基膦 以 丙酮 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Cyclometallated platinum compounds with N-benzylidenebenzylamines bearing trifluoromethyl groups. Crystal structure of [PtMe}3-(CF3) C6H3CHNCH2Ph{(PPh3)]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] (1) with the imine 3-(CF3)C6H4CH=NCH2Ph (2a) yields the cyclometallated compound [PtMe{3-(CF3)C6H3CH=NCH2Ph}(SMe2)] (3a) by selective metallation at the less hindered of the two ortho positions of the aryl ring followed by loss of methane. A similar reaction for imine 2-(CF3)C6H4CH=NCH2Ph (2c) yieIds the cyclometallated compound [PtMe{2-(CF3)C6H3CH=NCH2Ph} (SMe2)] (3c). The reactions of these compounds with triphenylphosphine in (1 : 1) ratio produce compounds [PtMe{3-(CF3)C6H3CH=NCH2Ph}(PPh3)] (4a) and [PtMe{2-(CF3)C6H3CH=NCH2Ph}(PPh3)] (4c). The X-ray structure of 4a is reported. An excess of triphenylphosphine produces metallacycle cleavage and [PtMe{3-(CF3)C6H3CH=NCH2Ph} (PPh3)(2)] (5a) is formed with the imine acting as a [C-] unidentate ligand. Oxidative addition of methyl iodide to compounds 4a and 4c gives cyclometallated platinum(IV) complexes. Imines 3,5-(CF3)(2)C6H3CH=NCH2Ph (2b) and 2-F-6-(CF3)C6H3CH=NCH2Ph (2d) fail to react with [Pt2Me4(mu-SMe2)(2)] (1). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00452-x
• 作为产物：
  描述：

  bis[dimethyl(μ-dimethylsulfide)platinum(II)] 、 Benzyl-[1-(2-trifluoromethyl-phenyl)-meth-(Z)-ylidene]-amine 以 丙酮 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Cyclometallated platinum compounds with N-benzylidenebenzylamines bearing trifluoromethyl groups. Crystal structure of [PtMe}3-(CF3) C6H3CHNCH2Ph{(PPh3)]

  摘要：

  The reaction of [Pt2Me4(mu-SMe2)(2)] (1) with the imine 3-(CF3)C6H4CH=NCH2Ph (2a) yields the cyclometallated compound [PtMe{3-(CF3)C6H3CH=NCH2Ph}(SMe2)] (3a) by selective metallation at the less hindered of the two ortho positions of the aryl ring followed by loss of methane. A similar reaction for imine 2-(CF3)C6H4CH=NCH2Ph (2c) yieIds the cyclometallated compound [PtMe{2-(CF3)C6H3CH=NCH2Ph} (SMe2)] (3c). The reactions of these compounds with triphenylphosphine in (1 : 1) ratio produce compounds [PtMe{3-(CF3)C6H3CH=NCH2Ph}(PPh3)] (4a) and [PtMe{2-(CF3)C6H3CH=NCH2Ph}(PPh3)] (4c). The X-ray structure of 4a is reported. An excess of triphenylphosphine produces metallacycle cleavage and [PtMe{3-(CF3)C6H3CH=NCH2Ph} (PPh3)(2)] (5a) is formed with the imine acting as a [C-] unidentate ligand. Oxidative addition of methyl iodide to compounds 4a and 4c gives cyclometallated platinum(IV) complexes. Imines 3,5-(CF3)(2)C6H3CH=NCH2Ph (2b) and 2-F-6-(CF3)C6H3CH=NCH2Ph (2d) fail to react with [Pt2Me4(mu-SMe2)(2)] (1). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00452-x