dipyridine(N,N'-bis(salicylideneaminato)ethylene)manganese(III) bis(trifluoromethanefulfonyl)amide | 1392475-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: dipyridine(N,N'-bis(salicylideneaminato)ethylene)manganese(III) bis(trifluoromethanefulfonyl)amide
• CAS: 1392475-09-0
• 化学式: C₂F₆NO₄S₂*C₂₆H₂₄MnN₄O₂
• 分子量: 759.589
• InChiKey: IBEZNWHHYRPXSS-XWTYAXFOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 diaqua(N,N'-bis(salicylideneaminato)ethylene)manganese(III) bis(trifluoromethanefulfonyl)amide 以 丙酮 为溶剂， 以97.1%的产率得到dipyridine(N,N'-bis(salicylideneaminato)ethylene)manganese(III) bis(trifluoromethanefulfonyl)amide
  参考文献：
  名称：

  Thermal properties and crystal structures of manganese(III)-salen complexes with the Tf2N anion [Tf2N=bis(trifluoromethanesulfonyl)amide)]

  摘要：

  A series of salts comprising cationic manganese(III)-salen complexes and the Tf2N anion has been prepared (salen = N.N'-bis(salicylideneaminato)ethylene, Tf2N = bis(trifluoromethanesulfonyl)amide) to investigate the effects of axial ligands and substituents on their thermal properties. [Mn(salen)L-2][Tf2N] (L= H2O, pyridine) and their 5-butoxysalen analogs undergo thermal desorption of the axial ligands, followed by decomposition above 250 degrees C. The pyridine complexes exhibit two-step ligand desorption, corresponding to the formation of a dimer and later, desorption from the dimer. Complexes with L = 3-butylpyridine and N-butylimidazole melt at 97.6 and 132.7 degrees C, respectively, before ligand desorption. Crystal structures of these and related complexes have been determined. [Mn(salen)(3,3'-bipyridine)][Tf2N] is a coordination polymer with higher thermal stability. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.004