trifluorotrimesic acid | 21892-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trifluorotrimesic acid
• 英文别名: Trifluortrimesinsaeure；2,4,6-Trifluorobenzene-1,3,5-tricarboxylic acid
• CAS: 21892-39-7
• 化学式: C₉H₃F₃O₆
• 分子量: 264.114
• InChiKey: RQJSYRKWKXIHEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  全氟-(1,3,5-三甲基苯) 在 水 、 五氟化锑 、 silica gel 作用下， 生成 trifluorotrimesic acid
  参考文献：
  名称：

  Karpov, V. M.; Panteleev, I. V.; Platonov, V. E., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, p. 1932 - 1938

  摘要：

  DOI：

文献信息

• METAL COMPLEX, AND ABSORBENT, OCCLUSION MATERIAL AND SEPARATION MATERIAL PRODUCED THEREFROM
  申请人：Kuraray Co., Ltd.

  公开号：EP2868649A1

  公开（公告）日：2015-05-06

  The metal complex comprises a multivalent carboxylic acid compound, at least one metal ion selected from ions of metals belonging to Groups 2 to 13 of the periodic table, an organic ligand capable of multidentate binding to the metal ion, and a C1 or C2 monocarboxylic acid compound. The metal complex has excellent gas adsorption, storage, and separation performance as well as excellent durability. The metal complex is stably present under high temperature and high humidity, and can maintain high adsorption performance.

  金属络合物由多价羧酸化合物、至少一种选自元素周期表第 2 至 13 族金属离子的金属离子、一种能与金属离子多价结合的有机配体以及一种 C1 或 C2 单羧酸化合物组成。金属络合物具有优异的气体吸附、储存和分离性能，以及出色的耐久性。金属络合物在高温高湿条件下也能稳定存在，并保持较高的吸附性能。
• METHOD FOR PRODUCING METAL COMPLEX
  申请人：Kuraray Co., Ltd.

  公开号：EP2960227A1

  公开（公告）日：2015-12-30

  Disclosed is a method for producing a metal complex comprising a multivalent carboxylic acid compound, at least one metal ion, an organic ligand capable of multidentate binding to the metal ion, and a monocarboxylic acid compound, wherein the metal ion is used in the form of a metal salt having a counter anion of the metal ion, a conjugate acid of the counter anion having a first dissociation exponent larger by 0 to 6 than that of the multivalent carboxylic acid compound, and at least one of the multivalent carboxylic acid compound, the metal ion, the organic ligand capable of multidentate binding, and the monocarboxylic acid compound is reacted in a suspended state. This method can effectively produce a metal complex.

  本发明公开了一种生产金属配合物的方法，该配合物由多价羧酸化合物、至少一种金属离子、一种能与金属离子多价结合的有机配体和一种单羧酸化合物组成，其中金属离子以金属盐的形式使用，该金属盐具有金属离子的阴离子、该阴离子的共轭酸的第一解离指数比多价羧酸化合物的第一解离指数大 0 至 6，并且多价羧酸化合物、金属离子、能与多价结合的有机配体和一元羧酸化合物中至少有一种是在悬浮状态下反应的。这种方法可以有效地生成金属络合物。
• METAL COMPLEX, AND ABSORBENT MATERIAL, STORAGE MATERIAL AND SEPARATION MATERIAL COMPRISING THE METAL COMPLEX
  申请人：Kuraray Co., Ltd.

  公开号：EP2868649B1

  公开（公告）日：2021-04-07
• METAL COMPLEX, AND ABSORBENT MATERIAL, STORAGE MATERIAL AND SEPARATION MATERIAL COMPRISING METAL COMPLEX
  申请人：KURARAY CO., LTD.

  公开号：US20150144085A1

  公开（公告）日：2015-05-28

  The metal complex comprises a multivalent carboxylic acid compound, at least one metal ion selected from ions of metals belonging to Groups 2 to 13 of the periodic table, an organic ligand capable of multidentate binding to the metal ion, and a C 1 or C 2 monocarboxylic acid compound. The metal complex has excellent gas adsorption, storage, and separation performance as well as excellent durability. The metal complex is stably present under high temperature and high humidity, and can maintain high adsorption performance.
• US9586170B2
  申请人：——

  公开号：US9586170B2

  公开（公告）日：2017-03-07