bis(6-amino-2-thiouracilato)aquacadmium(II) hydrate | 144058-04-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: bis(6-amino-2-thiouracilato)aquacadmium(II) hydrate
• CAS: 144058-04-8
• 化学式: C₈H₁₀CdN₆O₃S₂*H₂O
• 分子量: 432.763
• InChiKey: AQIVGQSWFOWNAZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(6-amino-2-thiouracilato)aquacadmium(II) hydrate 以 solid 为溶剂， 生成
  参考文献：
  名称：

  Thermal analysis applied to the study of metal complexes: thermal behaviour of 6-amino-2-thiouracil and its complexes with several transition metal ions

  摘要：

  The thermal decomposition processes of 6-amino-2-thiouracil and its Co(II), Ni(II), Cu(I), Ag(I), Zn(II), Cd(II) and Hg(II) complexes ha been studied by TG and DSC techniques. Heats of dehydration have been calculated from the DSC curves. Infrared spectroscopy applied to some of these complexes heated in air has elucidated thc decomposition steps and the nature of the intermediate products. The pyrolysis of these compounds ends between 600 and 800-degrees-C with different products as final residues.

  DOI：

  10.1016/0040-6031(92)85119-g
• 作为产物：
  描述：

  6-氨基-2-硫脲嘧啶 、 aqueous cadmium chloride 在 sodium acetate 作用下， 以 水 为溶剂， 生成 bis(6-amino-2-thiouracilato)aquacadmium(II) hydrate
  参考文献：
  名称：

  Thermal analysis applied to the study of metal complexes: thermal behaviour of 6-amino-2-thiouracil and its complexes with several transition metal ions

  摘要：

  The thermal decomposition processes of 6-amino-2-thiouracil and its Co(II), Ni(II), Cu(I), Ag(I), Zn(II), Cd(II) and Hg(II) complexes ha been studied by TG and DSC techniques. Heats of dehydration have been calculated from the DSC curves. Infrared spectroscopy applied to some of these complexes heated in air has elucidated thc decomposition steps and the nature of the intermediate products. The pyrolysis of these compounds ends between 600 and 800-degrees-C with different products as final residues.

  DOI：

  10.1016/0040-6031(92)85119-g

文献信息

• Transition metal complexes of 6-amino 2-thiouracil; crystal structure of bis(6-amino-2-thiouracilato)aquazinc(II) dihydrate
  作者：M. Angustias Romero、M. Purificación Sánchez、Miguel Quirós、Francisco Sánchez、Juan Manuel Salas、Miguel N. Moreno、René Faure

  DOI：10.1139/v93-004

  日期：1993.1.1

  Complexes of 6-amino-2-thiouracil (H2ATU) with the metal ions Ni(II), Co(II), Zn(II), Cd(II), Cu(I), Ag(I), and Hg(II) have been isolated and characterized by means of elemental analysis, infrared, NMR, and visible spectroscopies, and magnetic measurements. The crystal structure of [Zn(HATU)2(H2O)] • 2H2O has been solved by X-ray diffraction showing that the metal atom is five-coordinated by a water

  6-氨基-2-硫尿嘧啶 (H2ATU) 与金属离子 Ni(II)、Co(II)、Zn(II)、Cd(II)、Cu(I)、Ag(I) 和 Hg(II) 的配合物) 已通过元素分析、红外、核磁共振、可见光谱和磁测量进行分离和表征。[Zn(HATU)2(H2O)] • 2 的晶体结构已通过 X 射线衍射解析出，表明金属原子由一个水分子和两个通过硫和 N1 原子结合的配体进行五配位，关闭四元螯合环。漫反射光谱和磁测量表明 [Co(HATU)2( )] • 2 具有与锌配合物相似的结构，并且镍配合物 [Ni(HATU)2] 和 [Ni(HATU)2 ( )2] 分别具有四面体和 D4h 扭曲八面体环境。