4-(4-ethylcyclohexyl)cyclohexanecarbonyl chloride | 1118625-23-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: 4-(4-ethylcyclohexyl)cyclohexanecarbonyl chloride
• 英文别名: trans-4-(trans-4-Ethylcyclohexyl)cyclohexanecarboxylic acid chloride；4-(4-ethylcyclohexyl)cyclohexane-1-carbonyl chloride
• CAS: 1118625-23-2
• 化学式: C₁₅H₂₅ClO
• 分子量: 256.816
• InChiKey: WRZOHCRRNHPSMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-(4-ethylcyclohexyl)cyclohexanecarbonyl chloride 、 2,4-二氟苯酚 生成 trans-4-(trans-4-ethylcyclohexyl)cyclohexanecarboxylic acid-2,4-difluorophenyl ester
  参考文献：
  名称：

  SUGIMORI, SHIGERU;KOJIMA, TETSUHIKO

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(4-ethaneylcyclohexyl)cyclohexanecarboxylic acid 生成 4-(4-ethylcyclohexyl)cyclohexanecarbonyl chloride
  参考文献：
  名称：

  SUGIMORI, SHIGERU;KOJIMA, TETSUHIKO

  摘要：

  DOI：

文献信息

• HETEROCYCLIC COMPOUND, ULTRAVIOLET RAY ABSORBENT, AND COMPOSITION COMPRISING THE ULTRAVIOLET RAY ABSORBENT
  申请人：Fujifilm Corporation

  公开号：EP2177524A1

  公开（公告）日：2010-04-21

  A compound represented by formula (I-1): wherein R21, R22, R23 and R24 each independently represent a hydrogen atom or a monovalent substituent, with the proviso that compounds, in which R21, R22, R23 and R24 each are an alkylthio group, are excluded; R21 and R22 and/or R23 and R24 each may bond to each other to form a ring, with the proviso that compounds, in which the formed ring is a dithiol ring or a dithiolane ring, are excluded; R25 and R26 each independently represent a hydrogen atom or a monovalent substituent; X21, X22, X23 and X24 each independently represent a hetero atom; compounds, wherein R21, R22, R23 and R24 each represent a cyan group; X21, X22, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group or a hydrogen atom, are excluded; and compounds, wherein R21 and R23 each represent a hydrogen atom; R22 and R24 each represent an arylcarbonyl group; X21, X21, X23 and X24 each represent a sulfur atom; and R25 and R26 each represent a hydroxyl group, are excluded; and an ultraviolet absorbent, which has molecular weight of 10,000 or less and molar extinction coefficient at the maximum absorption wavelength of the ultraviolet absorbent of 80,000 or more.

  式 (I-1) 所代表的化合物： 其中 R21、R22、R23 和 R24 各自独立地代表氢原子或一价取代基，但不包括 R21、R22、R23 和 R24 各自为烷硫基的化合物；R21 和 R22 和/或 R23 和 R24 可相互键合形成环，但不包括所形成的环为二硫醇环或二硫环的化合物； R25和R26各自独立地代表氢原子或单价取代基； X21、X22、X23和X24各自独立地代表杂原子； 化合物，其中 R21、R22、R23 和 R24 各自代表一个氰基；X21、X22、X23 和 X24 各自代表一个硫原子；以及 R25 和 R26 各自代表一个羟基或一个氢原子。 化合物，其中 R21 和 R23 各代表一个氢原子；R22 和 R24 各代表一个芳羰基；X21、X21、X23 和 X24 各代表一个硫原子；以及 R25 和 R26 各代表一个羟基。
• POLYMERIZABLE COMPOSITION COMPRISING POLYMERIZABLE COMPOUNDS, FILM, AND HALF MIRROR FOR PROJECTED-IMAGE DISPLAY
  申请人：Fujifilm Corporation

  公开号：EP3199561A1

  公开（公告）日：2017-08-02

  The present invention provides a polymerizable composition having low birefringence which contains at least two types of polymerizable compounds represented by Formula (I): in the formula, A represents a phenylene or a trans-1,4-cyclohexylene, L represents -OC(=O)-, -OC(=O)O-, and the like, m represents 3 to 12, Sp1 and Sp2 represent an alkylene of which -CH2- may be substituted with -O- or the like, and the like, and Q1 and Q2 represent a polymerizable group, and the like, in which when a number obtained by dividing the number of trans-1,4-cyclohexylenes represented by A by m is set to mc, the polymerizable compounds include a polymerizable compound satisfying 0.5 < mc < 0.7 and a polymerizable compound satisfying 0.1 < mc < 0.3. A film such as a low birefringence phase difference film or a reflection film having high selectivity in a reflection wavelength range can be provided by using the polymerizable composition.

  本发明提供了一种具有低双折射的可聚合组合物，该组合物含有至少两种由式（I）表示的可聚合化合物： 式中，A 代表亚苯基或反式-1,4-环己烯，L 代表-OC(＝O)-、-OC(＝O)O-等，m 代表 3 至 12，Sp1 和 Sp2 代表其中-CH2-可被-O-等取代的亚烷基等、以及 Q1 和 Q2 代表可聚合基团等，其中，当将 A 所代表的反式-1,4-环己烯的数目除以 m 所得到的数字设为 mc 时，可聚合化合物包括满足 0.5 < mc < 0.7的可聚合化合物和满足0.1 < mc < 0.3的可聚合化合物。使用该可聚合组合物可以提供一种薄膜，例如低双折射相位差薄膜或在反射波长范围内具有高选择性的反射薄膜。
• Polymerizable composition containing polymerizable compound, film, and half mirror for displaying projection image
  申请人：FUJIFILM Corporation

  公开号：US10323120B2

  公开（公告）日：2019-06-18

  The present invention provides a polymerizable composition having low birefringence which contains at least two types of polymerizable compounds represented by Formula (I): Q1-Sp1A-LmSp2-Q2  (I) in the formula, A represents a phenylene or a trans-1,4-cyclohexylene, L represents —OC(═O)—, —OC(═O)O—, and the like, m represents 3 to 12, Sp1 and Sp2 represent an alkylene of which —CH2— may be substituted with —O— or the like, and the like, and Q1 and Q2 represent a polymerizable group, and the like, in which when a number obtained by dividing the number of trans-1,4-cyclohexylenes represented by A by m is set to mc, the polymerizable compounds include a polymerizable compound satisfying 0.5

  本发明提供了一种具有低双折射的可聚合组合物，该组合物含有至少两种由式（I）表示的可聚合化合物： Q1-Sp1A-LmSp2-Q2 (I) 式中，A 代表亚苯基或反式-1,4-环己烯，L 代表-OC(═O)-、-OC(═O)O-等，m 代表 3 至 12，Sp1 和 Sp2 代表其-CH2-可被-O-等取代的亚烷基等、以及 Q1 和 Q2 代表可聚合基团等，其中，当用 m 除以 A 所代表的反式-1,4-环己烯的数目所得的数字设为 mc 时，可聚合化合物包括满足 0.5
• Polymerizable compound, polymerizable composition, film, and half mirror for displaying projection image
  申请人：FUJIFILM Corporation

  公开号：US10457628B2

  公开（公告）日：2019-10-29

  The present invention provides a new polymerizable compound which is represented by Formula (I). In the formula, R1 indicates an alkyl group or the like, A represents a (m+n)valent cyclic group, L1 indicates a single bond or the like, L2 indicates —COO— or the like, Z indicates —COO— or the like, Sp indicates an alkylene group, an alkyleneoxy group, or the like, Q indicates a polymerizable group such as a (meth)acryloyl groups, 1 indicates an integer of 0 to 2, m indicates an integer of 1 or 2, and n indicates an integer of 1 to 3. The present invention also provides a polymerizable composition which includes the polymerizable compound described above, a film which is formed from the polymerizable composition described above, and a half mirror for displaying a projection image which includes the film described above. Using the polymerization composition described above, it is possible to manufacture films such as a low birefringence retardation film and a reflection film with high reflection wavelength region selectivity.

  本发明提供了一种新的可聚合化合物，由式（I）表示。式中，R1 表示烷基或类似物，A 表示(m+n)价环状基团，L1 表示单键或类似物，L2 表示-COO-或类似物，Z 表示-COO-或类似物，Sp 表示亚烷基、亚烷氧基或类似物，Q 表示可聚合基团，如(甲基)丙烯酰基，1 表示 0 至 2 的整数，m 表示 1 或 2 的整数，n 表示 1 至 3 的整数。本发明还提供了一种可聚合组合物，它包括上述可聚合化合物；一种薄膜，它由上述可聚合组合物形成；以及一种用于显示投影图像的半面镜，它包括上述薄膜。使用上述聚合组合物，可以制造出低双折射延缓膜和高反射波长区域选择性的反射膜等薄膜。
• EP2177524
  申请人：——

  公开号：——

  公开（公告）日：——