bis(tert-butylcyclopentadienyl)vanadium dichloride | 177790-38-4

• 分子结构分类: 有机化合物
• 英文名称: bis(tert-butylcyclopentadienyl)vanadium dichloride
• 英文别名: [V(η5-C5H4C(CH3)3)2Cl2]；(η5C5H4CMe3)2VCl2；5-tert-butylcyclopenta-1,3-diene;vanadium(4+);dichloride
• CAS: 177790-38-4
• 化学式: C₁₈H₂₆Cl₂V
• 分子量: 364.252
• InChiKey: OZAILODAYNQDRO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(tert-butylcyclopentadienyl)vanadium 在 盐酸 作用下， 以 not given 为溶剂， 生成 bis(tert-butylcyclopentadienyl)vanadium dichloride
  参考文献：
  名称：

  Moise, Claude; Reeb, Patrice; Mugnier, Yves, Comptes Rendus de l'Academie des Sciences - Serie II

  摘要：

  DOI：

文献信息

• A Facile and Efficient Method for Preparing Ring-Alkylated Vanadocenes (RCp)₂V and Mono- and Dichlorides of Ring-Alkylated Vanadocenes (RCp)₂VCl and (RCp)₂VCl₂
  作者：John A. Belot、Richard D. McCullough、Arnold L. Rheingold、Glenn P. A. Yap

  DOI：10.1021/om960349o

  日期：1996.11.12

  A convenient procedure for the general preparation of bis(methylcyclopentadienyl)vanadium (1), bis(isopropylcyclopentadienyl)vanadium (2), and bis(tert-butylcylopentadienyl)vanadium (3) and their blue monochloride (4-6) and green dichloride (7-9) derivatives is presented. The X-ray structures of compounds 8 and 9 and the electrochemistry and EPR of 7-9 are also presented.
• New 1,1?-Ring-substituted Vanadocene Dichlorides. Crystal structures of [V(?5-C5H4SiMe3)2Cl2] and [V(?5-C5H5)2Cl2]
  作者：Nektarios Tzavellas、Nikolaos Klouras、Caterina P. Raptopoulou

  DOI：10.1002/zaac.19966220526

  日期：1996.5

  AbstractThe 1,1′‐ring‐substituted vanadocene dichlorides [V(η5‐C5H4R)2Cl2] (R = CMe3, SiMe3, SiEt3) have been prepared from VCl4 and the appropriate lithiated cyclopentadiene, C5H4RLi, in 1 : 2 ratios. All complexes were characterized by elemental microanalysis and IR spectroscopy. The crystal structures of [V(η5‐C5H4SiMe3)2Cl2] 3 and the parent compound [V(η5‐C5H5)2Cl2] 1 have been determined by X‐ray diffraction and are in accordance with expectations. Compound 1 crystallizes with two crystallographically independent molecules in its monoclinic unit cell. These two molecules are quite similar in their essential structural features. Compound 3 crystallizes in the triclinic space group P1. The trimethylsilylcyclopentadienyl rings are bound in a staggered relative orientation.