2,2'-bis(2-hydroxy-5-trifluoro-benzylideneamino)-1.1'-naphthyl(III) complex | 1616063-27-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,2'-bis(2-hydroxy-5-trifluoro-benzylideneamino)-1.1'-naphthyl(III) complex
• CAS: 1616063-27-4
• 化学式: C₃₆H₂₁F₆MnN₂O₅
• 分子量: 730.502
• InChiKey: FUISZADPHXWIFP-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 2,2'-bis(2-hydroxy-5-trifluoromethoxy-benzylideneamino)-1.1'-naphthyl 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 3.0h， 以82%的产率得到2,2'-bis(2-hydroxy-5-trifluoro-benzylideneamino)-1.1'-naphthyl(III) complex
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity of chiral binaphthyl Schiff-base manganese complexes for the epoxidation of styrene

  摘要：

  Chiral binaphthyl Schiff base ligands were prepared by condensation of 2,2'-diamino-1,1'-binaphthalene with various salicylaldehydes. Ligands were coordinated with Mn(III) as catalysts. The catalytic efficiency of the complexes was tested on the epoxidation of styrene. The influences of the parameters such as reaction time, position of substituents with various oxidants on the epoxidation reactions were investigated. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.04.004
• 作为试剂：
  描述：

  苯乙烯 在 二叔丁基过氧化物 、 2,2'-bis(2-hydroxy-5-trifluoro-benzylideneamino)-1.1'-naphthyl(III) complex 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 (R)-环氧苯乙烷 、 (S)-环氧苯乙烷
  参考文献：
  名称：

  Synthesis, characterization and catalytic activity of chiral binaphthyl Schiff-base manganese complexes for the epoxidation of styrene

  摘要：

  Chiral binaphthyl Schiff base ligands were prepared by condensation of 2,2'-diamino-1,1'-binaphthalene with various salicylaldehydes. Ligands were coordinated with Mn(III) as catalysts. The catalytic efficiency of the complexes was tested on the epoxidation of styrene. The influences of the parameters such as reaction time, position of substituents with various oxidants on the epoxidation reactions were investigated. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.04.004