5-(2-methylpropoxy)-1-N',3-N'-bis[2-(2-methylpropoxy)benzoyl]benzene-1,3-dicarbohydrazide | 1206874-16-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(2-methylpropoxy)-1-N',3-N'-bis[2-(2-methylpropoxy)benzoyl]benzene-1,3-dicarbohydrazide
• CAS: 1206874-16-9
• 化学式: C₃₄H₄₂N₄O₇
• 分子量: 618.73
• InChiKey: HNUKVMCUFXWKJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  45
• 可旋转键数：
  13
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  144
• 氢给体数：
  4
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  、 o-Isobutoxy benzoic acid hydrazide 在 N,N-二异丙基乙胺 、 Methanaminium,N-[(dimethylamino)(3H-1,2,3-triazolo[4,5-b]pyridin-3-yloxy)methylene]-N-methyl-, hexafluorophosphate(1-) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以94%的产率得到5-(2-methylpropoxy)-1-N',3-N'-bis[2-(2-methylpropoxy)benzoyl]benzene-1,3-dicarbohydrazide
  参考文献：
  名称：

  Two novel quadruple hydrogen-bonding motifs: the formation of supramolecular polymers, vesicles, and organogels

  摘要：

  Two new hydrazide-based quadruple hydrogen-bonding motifs are described. Dipodals based on these two motifs are revealed to form supramolecular polymers, which can further aggregate to form vesicles and/or organogels in hydrocarbons. The quadruple hydrogen-bonding motifs are characterized by the Xray diffraction and (2D) H-1 NMR experiments, while the vesicles and organogels are evidenced by SEM, AFM TEM, and fluorescent microscopy. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.10.115

文献信息

• Two novel quadruple hydrogen-bonding motifs: the formation of supramolecular polymers, vesicles, and organogels
  作者：Ping Du、Gui-Tao Wang、Xin Zhao、Guang-Yu Li、Xi-Kui Jiang、Zhan-Ting Li

  DOI：10.1016/j.tetlet.2009.10.115

  日期：2010.1

  Two new hydrazide-based quadruple hydrogen-bonding motifs are described. Dipodals based on these two motifs are revealed to form supramolecular polymers, which can further aggregate to form vesicles and/or organogels in hydrocarbons. The quadruple hydrogen-bonding motifs are characterized by the Xray diffraction and (2D) H-1 NMR experiments, while the vesicles and organogels are evidenced by SEM, AFM TEM, and fluorescent microscopy. (C) 2009 Elsevier Ltd. All rights reserved.