N,N-bis(phenylmethyl)trimethylgermanecarboselenoamide | 1228095-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-bis(phenylmethyl)trimethylgermanecarboselenoamide
• 英文别名: N,N-dibenzyl-1-trimethylgermylmethaneselenoamide
• CAS: 1228095-89-3
• 化学式: C₁₈H₂₃GeNSe
• 分子量: 404.937
• InChiKey: PFJIQDDJOCBQND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.86
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N,N-dibenzylselenoformamide 、 三甲基氯化锗 在 diisopropylamine 、 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以42%的产率得到N,N-bis(phenylmethyl)trimethylgermanecarboselenoamide
  参考文献：
  名称：

  (Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization

  摘要：

  Deprotonation of the selenoformyl group in N,N-dibenzyl selenoformamide with LDA, followed by silylation and germylation of the resulting anion with Me(3)SiCl and Me(3)GeCl, gives (selenocarbamoyl)silane and -germane in moderate to good yields. The molecular structures of these products and the starting selenoformamide were characterized by using X-ray analyses.

  DOI：

  10.1021/om100290h

文献信息

• (Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization
  作者：Toshiaki Murai、Rumi Hori、Toshifumi Maruyama、Fumitoshi Shibahara

  DOI：10.1021/om100290h

  日期：2010.6.14

  Deprotonation of the selenoformyl group in N,N-dibenzyl selenoformamide with LDA, followed by silylation and germylation of the resulting anion with Me(3)SiCl and Me(3)GeCl, gives (selenocarbamoyl)silane and -germane in moderate to good yields. The molecular structures of these products and the starting selenoformamide were characterized by using X-ray analyses.