4,4'-diamino-5,5'dicyclohexyl-3,3'-dimethyldiphenylmethane | 885329-36-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-diamino-5,5'dicyclohexyl-3,3'-dimethyldiphenylmethane
• 英文别名: 4,4'-methylenebis(2-cyclohexyl-6-methylaniline)；4,4'-Diamino-5,5'-dicyclohexyl-3,3'-dimethyldiphenylmethane；4-[(4-amino-3-cyclohexyl-5-methylphenyl)methyl]-2-cyclohexyl-6-methylaniline
• CAS: 885329-36-2
• 化学式: C₂₇H₃₈N₂
• 分子量: 390.612
• InChiKey: RXWJURKZFBLEFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'-diamino-5,5'dicyclohexyl-3,3'-dimethyldiphenylmethane 、 3-叔丁基-2-羟基苯甲醛 在 甲酸 作用下， 以 甲醇 为溶剂， 以91%的产率得到6,6'-{methylenebis[(3-cyclohexyl-5-methyl-1,4-phenylene)iminomethyl]}bis(2-tert-butylphenol)
  参考文献：
  名称：

  Design of postmetallocene Schiff base-like catalytic systems for polymerization of olefins: XII. Synthesis of tetradentate bis-salicylaldehyde imine ligands

  摘要：

  Reactions of salicylaldehyde, 3-tert-butylsalicylaldehyde, and 3,5-di-tert-butylsalicylaldehyde with 1,4-diaminobutane, 1,6-diaminohexane, 4,4'-diaminodiphenylmethane, 4,4'-diamino-3,3',5,5'-tetramethyldiphenylmethane, 4,4'-diamino-5,5'-dicyclopentyl-3,3'-dimethyldiphenylmethane, 4,4'-diamino-5,5'-dicyclohexyl-3,3'-dimethyldiphenylmethane, bis(4-aminophenyl) sulfone, o,o'- and p,p'-diaminodiphenyl ethers, 1,4-bis(4-aminophenoxy)benzene, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, and 4,4aEuro(3)-diamino-p-terphenyl gave a series of the corresponding Schiff bases which can be used as tetradentate ligands for the synthesis of titanium and zirconium complexes.

  DOI：

  10.1134/s1070428009040101
• 作为产物：
  描述：

  2-cyclohexyl-6-methylaniline 、 聚合甲醛 在 盐酸 作用下， 以 水 为溶剂， 反应 6.17h， 以82%的产率得到4,4'-diamino-5,5'dicyclohexyl-3,3'-dimethyldiphenylmethane
  参考文献：
  名称：

  Design of postmetallocene Schiff base-like catalytic systems for polymerization of olefins: XII. Synthesis of tetradentate bis-salicylaldehyde imine ligands

  摘要：

  Reactions of salicylaldehyde, 3-tert-butylsalicylaldehyde, and 3,5-di-tert-butylsalicylaldehyde with 1,4-diaminobutane, 1,6-diaminohexane, 4,4'-diaminodiphenylmethane, 4,4'-diamino-3,3',5,5'-tetramethyldiphenylmethane, 4,4'-diamino-5,5'-dicyclopentyl-3,3'-dimethyldiphenylmethane, 4,4'-diamino-5,5'-dicyclohexyl-3,3'-dimethyldiphenylmethane, bis(4-aminophenyl) sulfone, o,o'- and p,p'-diaminodiphenyl ethers, 1,4-bis(4-aminophenoxy)benzene, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, and 4,4aEuro(3)-diamino-p-terphenyl gave a series of the corresponding Schiff bases which can be used as tetradentate ligands for the synthesis of titanium and zirconium complexes.

  DOI：

  10.1134/s1070428009040101

文献信息

• Design of postmetallocene catalytic systems of aryliminetype for olefins polymerization: XIII. Synthesis of tetradentate bis(2-hydroxy-1-naphthaldimine) ligands and their complexes with titanium(IV) dichloride
  作者：I. I. Oleinik、I. V. Oleinik、S. S. Ivanchev、G. A. Tolstikov

  DOI：10.1134/s1070428010050246

  日期：2010.5

  Reactions of 2-hydroxy-1-naphthaldehyde with 1,4-diaminobutane, 1,6-diaminohexane, 4,4'-methylenedianiline and its alkyl- and cycloalkyl-sybstituted derivatives, with 4,4'-sulfonyldianiline, 2,2'- and 4,4'-oxydianiline, 4,4'-(1,4-phenylenebisoxy)dianiline, 4,4'-[propane-2,2-diylbis(1,4-phenylenebisoxy)]dianiline, and p-terphenyl-4,4aEuro(3)-diamine afforded a series of the corresponding diimines that at treating with TiCl2(OPr-i)(2) formed mono- and binuclear complexes of titanium(IV) dichloride with tetradentate ligands LTiCl2 and L-2(TiCl2)(2).