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5,11-Dibutyltricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene | 47367-82-8

中文名称
——
中文别名
——
英文名称
5,11-Dibutyltricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene
英文别名
5,11-dibutyltricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene
5,11-Dibutyltricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene化学式
CAS
47367-82-8
化学式
C24H32
mdl
——
分子量
320.518
InChiKey
JGFZEURHSIIEEK-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    8.2
  • 重原子数:
    24
  • 可旋转键数:
    6
  • 环数:
    6.0
  • sp3杂化的碳原子比例:
    0.5
  • 拓扑面积:
    0
  • 氢给体数:
    0
  • 氢受体数:
    0

反应信息

  • 作为产物:
    描述:
    正溴丁烷二氯对二甲苯二聚体magnesium1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 作用下, 以 乙醚 为溶剂, 反应 60.0h, 以88%的产率得到5,11-Dibutyltricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene
    参考文献:
    名称:
    Synthesis, Structure, and Properties of Alkyl-Substituted PPXs by Chemical Vapor Deposition for Stent Coatings
    摘要:
    High-molecular-weight un-cross-linked poly(p-xylylene) (PPX) derivatives (3) with one lateral linear alkyl substituent (methyl octyl) on each phenylene moiety were prepared by pyrolysis of corresponding paracyclophanes followed by chemical vapor deposition (CVD). Most of these PPX derivatives showed good solubility in organic solvents which allowed purification by reprecipitation, structural analysis by solution NMR techniques, and molecular weight analysis by gel permeation chromatography. High thermal stability of 3 was found by thermogravimetric analysis. The glass transition temperatures decreased systematically with increasing alkyl chain length from 53 to -23 degrees C. Increased elongation to break up to 380% was analyzed by stress-strain experiments for as-deposited films indicating excellent coating properties, which were proven by initial coating tests on stents.
    DOI:
    10.1021/ma202270w
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文献信息

  • Synthesis, Structure, and Properties of Alkyl-Substituted PPXs by Chemical Vapor Deposition for Stent Coatings
    作者:Anna K. Bier、Michael Bognitzki、Jochen Mogk、Andreas Greiner
    DOI:10.1021/ma202270w
    日期:2012.2.14
    High-molecular-weight un-cross-linked poly(p-xylylene) (PPX) derivatives (3) with one lateral linear alkyl substituent (methyl octyl) on each phenylene moiety were prepared by pyrolysis of corresponding paracyclophanes followed by chemical vapor deposition (CVD). Most of these PPX derivatives showed good solubility in organic solvents which allowed purification by reprecipitation, structural analysis by solution NMR techniques, and molecular weight analysis by gel permeation chromatography. High thermal stability of 3 was found by thermogravimetric analysis. The glass transition temperatures decreased systematically with increasing alkyl chain length from 53 to -23 degrees C. Increased elongation to break up to 380% was analyzed by stress-strain experiments for as-deposited films indicating excellent coating properties, which were proven by initial coating tests on stents.
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