4,4'-bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl | 1104454-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl
• 英文别名: Trimethyl-[2-[3-[4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]phenyl]thiophen-2-yl]ethynyl]silane；trimethyl-[2-[3-[4-[4-[2-(2-trimethylsilylethynyl)thiophen-3-yl]phenyl]phenyl]thiophen-2-yl]ethynyl]silane
• CAS: 1104454-97-8
• 化学式: C₃₀H₃₀S₂Si₂
• 分子量: 510.871
• InChiKey: MPQLXLVAUSISPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.27
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,4'-bis(2-iodo-3-thienyl)biphenyl 、 三甲基乙炔基硅 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 17.0h， 以46.0 mg的产率得到4,4'-bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl
  参考文献：
  名称：

  Preparations of bis[2-(2-arylethynyl)-3-thienyl]arenes and bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]arenes

  摘要：

  4,4'-Bis[2-(2-phenylethynyl)-3-thienyl]biphenyl, 4,4'-bis[2-[2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl and their congeners were prepared and their properties were studied. Extension of pi-system through the central benzene ring was suggested by UV-vis spectra. Connection of two 1,4-bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]benzene units was exemplified. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.10.088

文献信息

• Preparations of bis[2-(2-arylethynyl)-3-thienyl]arenes and bis[2-{2-(trimethylsilyl)ethynyl}-3-thienyl]arenes
  作者：Kozo Toyota、Kazuyuki Okada、Hiroshi Katsuta、Noboru Morita

  DOI：10.1016/j.tet.2008.10.088

  日期：2009.1

  4,4'-Bis[2-(2-phenylethynyl)-3-thienyl]biphenyl, 4,4'-bis[2-[2-(trimethylsilyl)ethynyl}-3-thienyl]biphenyl and their congeners were prepared and their properties were studied. Extension of pi-system through the central benzene ring was suggested by UV-vis spectra. Connection of two 1,4-bis[2-2-(trimethylsilyl)ethynyl}-3-thienyl]benzene units was exemplified. (C) 2008 Elsevier Ltd. All rights reserved.