5,7,13,15,21,23,29,31-Octabenzyl-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31-hexadecazanonacyclo[25.5.1.13,9.111,17.119,25.04,8.012,16.020,24.028,32]hexatriacontane-6,14,22,30,33,34,35,36-octone | 1313763-37-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 5,7,13,15,21,23,29,31-Octabenzyl-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31-hexadecazanonacyclo[25.5.1.13,9.111,17.119,25.04,8.012,16.020,24.028,32]hexatriacontane-6,14,22,30,33,34,35,36-octone
• 英文别名: 5,7,13,15,21,23,29,31-octabenzyl-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31-hexadecazanonacyclo[25.5.1.13,9.111,17.119,25.04,8.012,16.020,24.028,32]hexatriacontane-6,14,22,30,33,34,35,36-octone
• CAS: 1313763-37-9
• 化学式: C₇₆H₇₂N₁₆O₈
• 分子量: 1337.51
• InChiKey: AUVWMGAORBOLFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  100
• 可旋转键数：
  16
• 环数：
  17.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  188
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  5,7,13,15,21,23,29,31-Octabenzyl-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31-hexadecazanonacyclo[25.5.1.13,9.111,17.119,25.04,8.012,16.020,24.028,32]hexatriacontane-6,14,22,30,33,34,35,36-octone 在 sodium disulfide 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Supramolecular binding and release of sulfide and hydrosulfide anions in water

  摘要：

  竹葡萄糖大环在水中结合并释放硫化物和氢硫化物阴离子。

  DOI：

  10.1039/c8cc00470f
• 作为产物：
  描述：

  2,4-dibenzylglycoluril 、 聚合甲醛 在 对甲苯磺酸 作用下， 以 氯仿 为溶剂， 反应 24.0h， 以57%的产率得到5,7,13,15,21,23,29,31-Octabenzyl-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31-hexadecazanonacyclo[25.5.1.13,9.111,17.119,25.04,8.012,16.020,24.028,32]hexatriacontane-6,14,22,30,33,34,35,36-octone
  参考文献：
  名称：

  Bambus[n]urils: a New Family of Macrocyclic Anion Receptors

  摘要：

  A recently discovered anion receptor is Jointed by three related macrocycles differing in the number of glycoluril units and type of substitution. The synthesis is carried out in nonpolar solvents compared to aqueous media used in the case of the original macrocycle. The size of macrocycle Is controlled by a template. A hexameric macrocycle with benzyl substitution binds halide anions with an affinity exceeding 10(9) M(-1) while a tetrameric analog does not bind any of the investigated anions.

  DOI：

  10.1021/ol201515c

文献信息

• Bambusurils Bearing Nitro Groups and Their Further Modifications
  作者：Mirza Arfan Yawer、Kristina Sleziakova、Lukas Pavlovec、Vladimir Sindelar

  DOI：10.1002/ejoc.201701329

  日期：2018.1.10

  Bambusurils are recently developed neutral anion receptors that show a high affinity towards many inorganic anions, not only in organic solvents but also in water. However, the number of water-soluble bambusurils and also those bearing functional groups is very limited. In this paper we report the synthesis of four- and six-membered bambusurils containing eight and twelve nitro groups. All the nitro

  Bambusurils 是最近开发的中性阴离子受体，对许多无机阴离子表现出高亲和力，不仅在有机溶剂中，而且在水中。然而，水溶性竹笋的数量以及带有官能团的竹材数量非常有限。在本文中，我们报告了含有八个和十二个硝基的四元和六元竹荪的合成。bambusuril 门户上的所有硝基都可以转化为氨基官能团，这为大环提供了水溶性并允许它们进一步修饰。例如，我们已经证明了竹柳上的氨基转化为相应的脲官能化竹柳衍生物。我们还报告了第一个仅带有两个官能团的竹子的例子，
• Bambus[<i>n</i>]urils: a New Family of Macrocyclic Anion Receptors
  作者：Vaclav Havel、Jan Svec、Michaela Wimmerova、Michal Dusek、Michaela Pojarova、Vladimir Sindelar

  DOI：10.1021/ol201515c

  日期：2011.8.5

  A recently discovered anion receptor is Jointed by three related macrocycles differing in the number of glycoluril units and type of substitution. The synthesis is carried out in nonpolar solvents compared to aqueous media used in the case of the original macrocycle. The size of macrocycle Is controlled by a template. A hexameric macrocycle with benzyl substitution binds halide anions with an affinity exceeding 10(9) M(-1) while a tetrameric analog does not bind any of the investigated anions.
• Supramolecular binding and release of sulfide and hydrosulfide anions in water
  作者：J. Vázquez、V. Sindelar

  DOI：10.1039/c8cc00470f

  日期：——

  Bambusuril macrocycles bind and release sulfide and hydrosulfide anions in water.

  竹葡萄糖大环在水中结合并释放硫化物和氢硫化物阴离子。