| 1051930-74-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯氮卓类
• CAS: 1051930-74-5
• 化学式: Br*C₇₂H₈₂N₁₆O₁₈Sm
• 分子量: 1689.8
• InChiKey: WNHFNTRZZRSPMM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  42,43,44-Trihydroxy-1,4,12,15,18,26,31,39-octazapentacyclo[13.13.13.16,10.120,24.133,37]tetratetraconta-6(44),7,9,20,22,24(43),33(42),34,36-nonaene-5,11,19,25,32,38-hexone 、 六水溴化钐 以 水 为溶剂， 生成
  参考文献：
  名称：

  Stable Lanthanide Luminescence Agents Highly Emissive in Aqueous Solution:  Multidentate 2-Hydroxyisophthalamide Complexes of Sm³⁺, Eu³⁺, Tb³⁺, Dy³⁺

  摘要：

  Efficient lanthanide (Ln) luminescent probes require good ligand-to-metal energy transfer and high aqueous stability. A family of ligands based on 2-hydroxyisophthalamide chelating units is reported. These form highly stable, eight-coordinate Ln complexes. Several of these (Ln = Sm, Eu, Tb, Dy) emit in the visible region with good ligand-to-lanthanide energy transfer. The absolute quantum yields of the two Tb complexes studies (Phi = 0.59, 0.61) and high absorbance make these the brightest luminescent probes for time-resolved detection; the emission spectrum of one complex can be seen down to 10-15 M. The low overlap of the four different Ln complexes enables their simultaneous detection and discrimination.

  DOI：

  10.1021/ja0379363