(4'-methyl[biphenyl]-4-yl)benzo[d]oxazole | 49743-93-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4'-methyl[biphenyl]-4-yl)benzo[d]oxazole
• 英文别名: Mebpbo；2-(4'-methyl-biphenyl-4-yl)-benzooxazole；2-[4-(4-Methylphenyl)phenyl]-1,3-benzoxazole；2-[4-(4-methylphenyl)phenyl]-1,3-benzoxazole
• CAS: 49743-93-3
• 化学式: C₂₀H₁₅NO
• 分子量: 285.345
• InChiKey: GSVGWDVDUHQTST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  26
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride trihydrate 、 (4'-methyl[biphenyl]-4-yl)benzo[d]oxazole 以 乙二醇乙醚 、 水 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Highly phosphorescent iridium(iii) complexes based on 2-(biphenyl-4-yl)benzo[d]oxazole derivatives: synthesis, structures, properties and DFT calculations

  摘要：

  已合成了一系列基于2-(联苯基-4-基)苯并[d]噁唑的双环金属化铱(iii)配合物，并展示了它们的高量子效率。

  DOI：

  10.1039/c5nj00975h
• 作为产物：
  描述：

  4-溴苯甲酸 在 palladium bis[bis(diphenylphosphino)ferrocene] dichloride 、 potassium acetate 作用下， 以 1,4-二氧六环 为溶剂， 反应 12.0h， 生成 (4'-methyl[biphenyl]-4-yl)benzo[d]oxazole
  参考文献：
  名称：

  Highly phosphorescent iridium(iii) complexes based on 2-(biphenyl-4-yl)benzo[d]oxazole derivatives: synthesis, structures, properties and DFT calculations

  摘要：

  已合成了一系列基于2-(联苯基-4-基)苯并[d]噁唑的双环金属化铱(iii)配合物，并展示了它们的高量子效率。

  DOI：

  10.1039/c5nj00975h

文献信息

• DISPLAY
  申请人：Novaled GmbH

  公开号：EP3561876A1

  公开（公告）日：2019-10-30

  Display comprising at least one organic light emitting diode, wherein the at least one organic light emitting diode comprises an anode, a cathode, a light emitting layer between the anode and the cathode, and at least one layer comprising a compound according to formula (I) between the cathode and the light emitting layer: wherein A1 and A2 are independently selected from halogen, CN, substituted or unsubstituted C1-C20-alkyl or heteroalkyl, C6-C20-aryl or C5-C20-heteroaryl, C1-C20-alkoxy or C6-C20-aryloxy, A3 is selected from substituted or unsubstituted C6-C40-aryl or C5-C40-heteroaryl, m = 0, 1 or 2, n = 0, 1 or 2.

  显示屏，包括至少一个有机发光二极管，其中至少一个有机发光二极管包括阳极、阴极、阳极和阴极之间的发光层，以及阴极和发光层之间至少一层包括式（I）化合物的层： 其中 A1 和 A2 独立选自卤素、CN、取代或未取代的 C1-C20 烷基或杂烷基、C6-C20 芳基或 C5-C20 异芳基、C1-C20 烷氧基或 C6-C20 芳氧基、 A3 选自取代或未取代的 C6-C40 芳基或 C5-C40 异芳基、 m = 0、1 或 2、 n = 0、1 或 2。
• Aerobic Oxidation of Alcohols and the Synthesis of Benzoxazoles Catalyzed by a Cuprocupric Coordination Polymer (Cu⁺-CP) Assisted by TEMPO
  作者：Xun Feng、Chen Xu、Zhi-Qiang Wang、Si-Fu Tang、Wei-Jun Fu、Bao-Ming Ji、Li-Ya Wang

  DOI：10.1021/ic502884z

  日期：2015.3.2

  A Cu+-CP based on the tetranuclear unit [(HSQPA)(2)Cu-4(bipy)4(]).2H(2)O}n.2nH(2)O has been constructed through Cu2+ salt, 2-(sulfonylquinlium-8-yloxy)phthalic acid (H3(S)QPA), and 4,4'-bipyridine (bipy). This Cu+-CP combined with 2,2,6,6-tetramethylpiperidine-1-oxyl as the cocatalyst is an effective catalyst for aerobic oxidation of alcohols and the synthesis of benzoxazoles and can be recycled at least four times without losing its catalytic activity.
• Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20200388779A1

  公开（公告）日：2020-12-10

  A light-emitting device with low driving voltage and favorable reliability is provided. The light-emitting device includes an electron-injection layer between a cathode and a light-emitting layer. The electron-injection layer is a mixed film of a metal and an organic compound having a function of interacting with the metal as a tridentate or tetradentate ligand, and the metal atom and the organic compound form SOMO.
• Highly phosphorescent iridium(<scp>iii</scp>) complexes based on 2-(biphenyl-4-yl)benzo[d]oxazole derivatives: synthesis, structures, properties and DFT calculations
  作者：Zhi-Gang Niu、Tao Zheng、You-Hui Su、Peng-Jiang Wang、Xiao-Yan Li、Feng Cui、Jiao Liang、Gao-Nan Li

  DOI：10.1039/c5nj00975h

  日期：——

  A series of new 2-(biphenyl-4-yl)benzo[d]oxazole based bis-cyclometalated iridium(iii) complexes have been synthesized, and their high quantum efficiency are presented.

  已合成了一系列基于2-(联苯基-4-基)苯并[d]噁唑的双环金属化铱(iii)配合物，并展示了它们的高量子效率。