Methyl-cyclohexylphosphin | 90050-09-2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: Methyl-cyclohexylphosphin
• 英文别名: Cyclohexyl(methyl)phosphane
• CAS: 90050-09-2
• 化学式: C₇H₁₅P
• 分子量: 130.17
• InChiKey: LZHZWOQYIORILC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Methyl-cyclohexylphosphin 、 环已基膦 在 [κ⁵-N,N,N,N,C-(Me₃SiNCH₂CH₂)₂NCH₂CH₂NSiMe₂CH₂]Zr 作用下， 以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  锆催化膦杂脱氢偶联反应的选择性效应

  摘要：

  图形摘要摘要已知锆化合物催化脱氢偶合膦。对可能促进选择性异脱氢偶联的因素进行了探索，发现空间因素很重要，但不能提供实质性的选择性。据观察，κ5-(Me3SiNCH2CH2)2N(CH2CH2NSiMe2CH2)Zr (1) 可能具有足够的路易斯酸性以进行路易斯酸或受挫的路易斯对催化。

  DOI：

  10.1080/10426507.2015.1128933

文献信息

• Alkyl Group VA metal compounds
  申请人：Shipley Company, L.L.C.

  公开号：US20030181746A1

  公开（公告）日：2003-09-25

  Disclosed are methods of preparing monoalkyl Group VA metal dihalide compounds in high yield and high purity by the reaction of a Group VA metal trihalide with an organo lithium reagent or a compound of the formula R n M 1 X 3−n , where R is an alkyl, M 1 is a Group IIIA metal, X is a halogen and n is an integer fro 1 to 3. Such monoalkyl Group VA metal dihalide compounds are substantially free of oxygenated impurities, ethereal solvents and metallic impurities. Monoalkyl Group VA metal dihydride compounds can be easily produced in high yield and high purity by reducing such monoalkyl Group VA metal dihalide compounds.

  揭示了通过将VA族金属三卤化物与有机锂试剂或具有公式RnM1X3−n的化合物（其中R是烷基，M1是III A族金属，X是卤素，n是1到3的整数）反应，以高产率和高纯度制备单烷基VA族金属二卤化合物的方法。这种单烷基VA族金属二卤化合物基本上不含氧杂质、醚溶剂和金属杂质。通过还原这种单烷基VA族金属二卤化合物，可以轻松地高产率和高纯度地生产单烷基VA族金属二氢化合物。
• Alkyl group VA metal compounds
  申请人：Shenai-Khatkhate Vinayak Deodatta

  公开号：US20050033073A1

  公开（公告）日：2005-02-10

  A method of preparing Group VA organometal compounds in high yield and high purity by the reaction of a Grignard reagent with a Group VA metal halide in certain ethereal solvents is provided. A method of preparing Group VA organometal hydrides is also provided.

  提供了一种通过格氏试剂与VA族金属卤化物在特定的醚溶剂中反应制备高收率和高纯度VA族有机金属化合物的方法。还提供了一种制备VA族有机金属氢化物的方法。
• Phosphorus substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20050239980A1

  公开（公告）日：2005-10-27

  This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR 2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R n where each R n is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R n substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  本发明涉及一种由以下公式表示的金属茂化合物：其中M是3、4、5或6族过渡金属原子、镧系金属原子或锕系金属原子；E是一个在茂环的2位被PR2基取代的茚烯配体，其中每个R都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物或取代的卤代碳氢化合物基团，此外，E可以被0、1、2、3、4、5或6个Rn取代，其中每个Rn都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物、取代的卤代碳氢化合物、硅基碳氢化合物、取代的硅基碳氢化合物、锗基碳氢化合物或取代的锗基碳氢化合物基团，而且，两个或更多相邻的Rn取代基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基团；A是一个取代或未取代的环戊二烯基配体、取代或未取代的杂环戊二烯基配体、取代或未取代的茚烯配体、取代或未取代的杂茚烯配体、取代或未取代的芴基配体、取代或未取代的杂芴基配体或其他单阴离子配体，或者A可以独立地被定义为E或X；每个X都是独立的一价阴离子配体，或者两个X结合并与金属原子结合形成金属环烷基，或两个X结合形成螯合配体、二烯配体或烷基亚胺配体。
• Preparation of monoalkyl group 15 metal dihalides and dihydrides
  申请人：Shipley Co. L.L.C.

  公开号：EP1335416A1

  公开（公告）日：2003-08-13

  Disclosed are methods of preparing monoalkyl Group VA metal dihalide compounds in high yield and high purity by the reaction of a Group VA metal trihalide with an organo lithium reagent or a compound of the formula RnM1X3-n where R is an alkyl, M1 is a Group IIIA metal, X is a halogen and n is an integer fro 1 to 3. Such monoalkyl Group VA metal dihalide compounds are substantially free of oxygenated impurities, ethereal solvents and metallic impurities. Monoalkyl Group VA metal dihydride compounds can be easily produced in high yield and high purity by reducing such monoalkyl Group VA metal dihalide compounds.

  公开了通过 VA 族金属三卤化物与有机锂试剂或式 RnM1X3-n 的化合物反应制备高产率和高纯度的单烷基 VA 族金属二卤化物化合物的方法，其中 R 为烷基，M1 为 IIIA 族金属，X 为卤素，n 为 1 至 3 的整数。通过还原这种单烷基 VA 族金属二卤化物化合物，可以很容易地生产出高产率和高纯度的单烷基 VA 族金属二氢化物化合物。
• FUSED QUINOLINE DERIVATIVE AND USE THEREOF
  申请人：Takeda Pharmaceutical Company Limited

  公开号：EP1740584B1

  公开（公告）日：2008-12-03