(2-[Me2NCH2CH2N(Me)CH2]C6H4)SnPh3 | 237058-32-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-[Me2NCH2CH2N(Me)CH2]C6H4)SnPh3
• CAS: 237058-32-1
• 化学式: C₃₀H₃₄N₂Sn
• 分子量: 541.323
• InChiKey: NVGBQZGIVUSGIR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  三苯基氯化锡 、 2-[(n,N,N'-trimethylethylenediamino)methyl]phenyllithium 以 四氢呋喃 为溶剂， 以67%的产率得到(2-[Me2NCH2CH2N(Me)CH2]C6H4)SnPh3
  参考文献：
  名称：

  Synthesis and structures of 2-[Me2NCH2CH2N(Me)CH2]C6H4 substituted tin compounds

  摘要：

  ArNNSnPh3 and (Ar-NN)(2)SnMe2 were prepared by reaction of LiArNN (Ar-NN = 2-[Me2NCN2CH2N(Me)CH2]C6H4) with stoichiometric amounts of the corresponding organotin chlorides. A mixture of ArNNSn(Cl)Me-2 and (Ar-NN)(2)SnMe2 was obtained when Me2SnCl2 was reacted with only one equivalent of LiArNN. The X-ray structure analysis and spectroscopic data of ArNNSnPh3 show that only the inner nitrogen atom of the Ar-NN ligand weakly interacts with the tin atom. The compound [Me-2(Cl)SnC6H4CH2N(Me)CH2CH2NHMe2]Cl was obtained by slow hydrolysis of ArNNSn(Cl)Me-2. It has a trigonal-bipyramidal structure by intramolecular coordination of the inner nitrogen atom, and a dangling CH2CH2NHMe2+ group. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00121-8