| 147993-55-3

• 分子结构分类: 有机化合物
• CAS: 147993-55-3
• 化学式: C₁₁
• 分子量: 132.121
• InChiKey: STZPNYVHYMBNJU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  graphite 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Linear C11 cluster: an isotopic infrared study

  摘要：

  Carbon clusters, formed by laser ablation of graphite and deposited in argon, krypton or nitrogen matrices, have been studied by Fourier transform infrared spectroscopy. Three bands at 1942.6, 1854.8 and 1357.0 cm(-1) (in N-2) have been attributed to linear C-11 with the aid of density functional theory (B3-LYP/6-31G*) calculations. Isotopomeric peak positions, observed after single C-13 substitution in the C-11 chain, were compared to predicted isotopic patterns, with excellent agreement found for the isolated weak 1357 cm(-1) band. Satisfactory agreement for the two more intense, close-lying peaks has been attributed to mode mixing due to symmetry breakdown upon the introduction of C-13. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(98)01374-8