(o-nitronyl nitroxide-phenyl)diphenylphosphine oxide | 190662-32-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (o-nitronyl nitroxide-phenyl)diphenylphosphine oxide
• CAS: 190662-32-9
• 化学式: C₂₅H₂₆N₂O₃P
• 分子量: 433.467
• InChiKey: QHZHXAJHPWCEJH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (o-nitronyl nitroxide-phenyl)diphenylphosphine oxide 、 bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)manganese(II) trihydrate 以 正庚烷 、 二氯甲烷 为溶剂， 以30%的产率得到[(o-nitronyl nitroxide-phenyl)diphenylphosphine oxide]bis(hexafluoroacetylacetonato)manganese(II)
  参考文献：
  名称：

  Rancurel, Corinne; Leznoff, Daniel B.; Sutter, Jean-Pascal, Inorganic Chemistry, 1999, vol. 38, p. 4753 - 4758

  摘要：

  DOI：

文献信息

• A Linear, Four-Spin Mn(II)−Nitronyl−Nitroxide-Substituted Phosphine Oxide System Exhibiting Both Antiferro- and Ferromagnetic Interactions
  作者：Corinne Rancurel、Daniel B. Leznoff、Jean-Pascal Sutter、Philippe Guionneau、Daniel Chasseau、Janis Kliava、Olivier Kahn

  DOI：10.1021/ic9909678

  日期：2000.4.1

  [oPONit]MnCl(mu-Cl)}(2) is a di-chloro-bridged Mn(II) binuclear compound in which each Mn(II) is coordinated by (o-nitronyl nitroxide-phenyl)diphenylphosphine oxide acting as a bidentate ligand via the oxygen atoms of the P=O and N-O groups. The spectrum of the low-lying states has been deduced from the magnetic and EPR properties. Antiferromagnetic Mn-radical and ferromagnetic Mn-Mn interactions lead to a S = 4 ground state.