1,3-bis(dimethylamino)-2-<(4-methylphenyl)sulfonyl>-1-propene | 130983-88-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis(dimethylamino)-2-<(4-methylphenyl)sulfonyl>-1-propene
• 英文别名: (Z)-N,N,N',N'-tetramethyl-2-(4-methylphenyl)sulfonylprop-1-ene-1,3-diamine
• CAS: 130983-88-9
• 化学式: C₁₄H₂₂N₂O₂S
• 分子量: 282.407
• InChiKey: HMQCLFJMZGDYFK-UVTDQMKNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  49
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-<(4-methylphenyl)sulfonyl>-1,1,5,5-tetramethyl-1,5-diazapentadienium perchlorate 在 sodium tetrahydroborate 作用下， 以 异丙醇 为溶剂， 反应 22.0h， 生成 1,3-bis(dimethylamino)-2-<(4-methylphenyl)sulfonyl>-1-propene
  参考文献：
  名称：

  The preparation and some reactions of 2-(arylsulfonyl)vinamidinium salts

  摘要：

  The preparation of novel 2-(arylsulfonyl)vinamidinium salts is described. The reactions of these materials with amidines, hydrazine, hydroxylamine, sodium borohydride, and Grignard reagents are presented along with an evaluation of their chemical behavior as compared to the 2-arylvinamidinium salts.

  DOI：

  10.1021/jo00003a015

文献信息

• The preparation and some reactions of 2-(arylsulfonyl)vinamidinium salts
  作者：John T. Gupton、Steve W. Riesinger、Ajit S. Shah、John E. Gall、Kathy M. Bevirt

  DOI：10.1021/jo00003a015

  日期：1991.2

  The preparation of novel 2-(arylsulfonyl)vinamidinium salts is described. The reactions of these materials with amidines, hydrazine, hydroxylamine, sodium borohydride, and Grignard reagents are presented along with an evaluation of their chemical behavior as compared to the 2-arylvinamidinium salts.