1,3-bis(pyrazol-1-yl)propane-2,2'-bipyridylnitratocopper(II) nitrate | 1356614-12-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,3-bis(pyrazol-1-yl)propane-2,2'-bipyridylnitratocopper(II) nitrate
• CAS: 1356614-12-4
• 化学式: C₁₉H₂₀CuN₇O₃*NO₃
• 分子量: 519.964
• InChiKey: XRSSHQPYOKBEPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  水 、 1,3-bis(pyrazol-1-yl)propane-2,2'-bipyridylnitratocopper(II) nitrate 以 乙醇 为溶剂， 生成 copper;2-pyridin-2-ylpyridine;dinitrate;hydrate
  参考文献：
  名称：

  Synthesis and crystal structure of discrete complexes and coordination polymers containing 1,3-bis(pyrazol-1-yl)propane ligands

  摘要：

  Complexes of 1,3-bis(pyrazole-1-yl)propane ligands with copper(II), nickel(II) and cobalt(II) ions were prepared and characterized by spectral methods and X-ray crystallography. Ligands with metal nitrates are chelating bidentate forming discrete complexes with eight-membered metallocycles. The structure of nickel(II) nitrate complex with 1,3-bis(3,5-dimethylpyrazol-1-yl)propane was determined by X-ray crystallography. In case of copper(II) chloride 1,3-bis(pyrazole-1-yl)propane adopted a bridging bidentate mode and a linear coordination polymer containing 16-membered metallocycles was formed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.039
• 作为产物：
  描述：

  2,2'-联吡啶 、 1,3-bis(pyrazol-1-yl)propanedinitratocopper 以 丙酮 为溶剂， 以74%的产率得到1,3-bis(pyrazol-1-yl)propane-2,2'-bipyridylnitratocopper(II) nitrate
  参考文献：
  名称：

  Synthesis and crystal structure of discrete complexes and coordination polymers containing 1,3-bis(pyrazol-1-yl)propane ligands

  摘要：

  Complexes of 1,3-bis(pyrazole-1-yl)propane ligands with copper(II), nickel(II) and cobalt(II) ions were prepared and characterized by spectral methods and X-ray crystallography. Ligands with metal nitrates are chelating bidentate forming discrete complexes with eight-membered metallocycles. The structure of nickel(II) nitrate complex with 1,3-bis(3,5-dimethylpyrazol-1-yl)propane was determined by X-ray crystallography. In case of copper(II) chloride 1,3-bis(pyrazole-1-yl)propane adopted a bridging bidentate mode and a linear coordination polymer containing 16-membered metallocycles was formed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.039