[Cu(3-hydroxy-5-hydroxymethyl-2-methyl-4-pyridinecarboxaldehyde semicarbazone)(NO2)2(CH3OH)] | 1265910-20-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(3-hydroxy-5-hydroxymethyl-2-methyl-4-pyridinecarboxaldehyde semicarbazone)(NO2)2(CH3OH)]
• CAS: 1265910-20-0
• 化学式: C₁₀H₁₆CuN₆O₁₀
• 分子量: 443.817
• InChiKey: DEEVYKNYLQSQCR-JMSZLRHESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) nitrate trihydrate 、 3-hydroxy-5-hydroxymethyl-2-methyl-4-pyridinecarboxaldehyde semicarbazone dihydrate 以 甲醇 为溶剂， 以42%的产率得到[Cu(3-hydroxy-5-hydroxymethyl-2-methyl-4-pyridinecarboxaldehyde semicarbazone)(NO2)2(CH3OH)]
  参考文献：
  名称：

  Synthesis, characterization and structural analysis of new copper(II) complexes incorporating a pyridoxal-semicarbazone ligand

  摘要：

  The reaction between 3-hydroxy-5-hydroxymethyl-2-methyl-4-pyridinecarboxaldehyde semicarbazone (pyridoxal-semicarbazone or PLSC) and appropriate chloride, sulfate, nitrate or thiocyanate Cu(II) salts in water/alcohol mixtures resulted in the formation of new copper(II) complexes: [Cu(PLSC)Cl-2] (1), [Cu(PLSC)(H2O)(SO4)](2)center dot 3H(2)O (2), [Cu-2(PLSC)(2)(NCS)(2)](NCS)(2) (3), [Cu(PLSC)(NO3)(2)(CH3OH)] (4) and [Cu(PLSC-2H]NH3 center dot H2O (5). The complexes were characterized by elemental analysis, conductometric measurements and IR spectroscopy, while complexes 1, 2, 3 and 4 were further characterized by single crystal X-ray diffraction. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.09.022