2-(2,6-Diphenylpyran-4-ylidene)-2-pyridin-4-ylacetaldehyde | 1211094-73-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(2,6-Diphenylpyran-4-ylidene)-2-pyridin-4-ylacetaldehyde
• 英文别名: 2-(2,6-diphenylpyran-4-ylidene)-2-pyridin-4-ylacetaldehyde
• CAS: 1211094-73-3
• 化学式: C₂₄H₁₇NO₂
• 分子量: 351.404
• InChiKey: ONGLVKARJMYWDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  39.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  草酰氯 、 4-[(2,6-Diphenylpyran-4-ylidene)methyl]pyridine 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到2-(2,6-Diphenylpyran-4-ylidene)-2-pyridin-4-ylacetaldehyde
  参考文献：
  名称：

  Ferrocenyl and pyridyl methylenepyrans as potential precursors of organometallic electron-rich extended bipyrans: Synthesis, characterization and crystal structure

  摘要：

  Ferrocenyl and pyridyl methylenepyrans were obtained from a Wittig reaction between a pyran phosphorane and ferrocenyl or pyridyl-aldehydes. The nucleophilic nature of the exocyclic C-C bond allowed the formylation of these compounds by a Vilsmeier type reaction. All the new products were characterized by IR spectroscopy, H-1 and C-13 NMR spectroscopy, mass spectroscopy and (or) elemental analysis. Electrochemistry of representative compounds 2, 10 and 13 was undertaken.In addition, a crystal structure of the ferrocenylpyranylidene aldehyde 5 was described, and the pyrylium character of this compound was specified. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.10.006

文献信息

• Ferrocenyl and pyridyl methylenepyrans as potential precursors of organometallic electron-rich extended bipyrans: Synthesis, characterization and crystal structure
  作者：Fatou Ba、Francoise Robin-Le Guen、Nolwenn Cabon、Pascal Le Poul、Stéphane Golhen、Nicolas Le Poul、Bertrand Caro

  DOI：10.1016/j.jorganchem.2009.10.006

  日期：2010.1

  Ferrocenyl and pyridyl methylenepyrans were obtained from a Wittig reaction between a pyran phosphorane and ferrocenyl or pyridyl-aldehydes. The nucleophilic nature of the exocyclic C-C bond allowed the formylation of these compounds by a Vilsmeier type reaction. All the new products were characterized by IR spectroscopy, H-1 and C-13 NMR spectroscopy, mass spectroscopy and (or) elemental analysis. Electrochemistry of representative compounds 2, 10 and 13 was undertaken.In addition, a crystal structure of the ferrocenylpyranylidene aldehyde 5 was described, and the pyrylium character of this compound was specified. (C) 2009 Elsevier B.V. All rights reserved.