Ag(DPK)2ClO3 | 267885-77-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ag(DPK)2ClO3
• CAS: 267885-77-8
• 化学式: C₂₂H₁₆AgClN₄O₅
• 分子量: 559.714
• InChiKey: UQKPVLDNDJYDPC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium chlorate 、 2-二吡啶基酮 、 silver sulfate 以 水 为溶剂， 以50%的产率得到Ag(DPK)2ClO3
  参考文献：
  名称：

  Systematic study of synthesis and crystal structures of Ag(DPK)nX complexes (DPK=di-2-pyridyl ketone; X=NO2−, ClO4−, ClO3−, PF6−, n=1; X=ClO4−, ClO3−, n=2): role of anion and π–π stacking interaction

  摘要：

  Six complexes formulated as Ag(DPK;)X (DPK = di-2-pyridyl ketone; X = NO2- ClO3-, ClO4-, PF6-) and Ag(DPK)(2)X (X = ClO3-, ClO4-) have been prepared and their structures have been determined by X-ray diffraction, showing that both ihe anion coordination and pi-pi stacking interaction play important roles in the solid structures of these complexes. The Ag(DPK)X complexes exhibit three kinds of helical structures and interesting structural variations within the series resulted from the different coordination modes of the anions. In Ag(DPK)(2)X, each DPK ligand coordinates to an Ag(I) atom through one of its pyridyl group in an unprecedented monodentate mode. The mononuclear complexes are stabilized by the intramolecular pi-pi stacking interactions and aligned into chains through the intermolecular pi-pi stacking interactions in a zipper-like fashion. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00522-8