OsH(NCCHCN)(tmen)(triphenylphosphine)2 | 847481-92-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: OsH(NCCHCN)(tmen)(triphenylphosphine)2
• 英文别名: OsH(NCCHCN)(2,3-diamino-2,3-dimethylbutane)(triphenylphosphine)2
• CAS: 847481-92-9
• 化学式: C₄₅H₄₈N₄OsP₂
• 分子量: 897.05
• InChiKey: YKXOMHBJXMJUMW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  RuH(NHC(methyl)₂C(methyl)₂NH₂)(P(phenyl)₃)₂ 、 OsH(NCCHCN)(tmen)(triphenylphosphine)2 以 氘代苯 为溶剂， 生成 OsH(NHCMe₂CMe₂NH₂)(PPh₃)₂ 、 trans-RuH(malononitrile(-1H))(2,3-diamino-2,3-dimethylbutane)(PPh3)2
  参考文献：
  名称：

  Reactions of an Amido Hydrido Complex of Osmium, OsH(NHCMe₂CMe₂NH₂)(PPh₃)₂:  HX Addition, HX Transfer, and Ketone H₂ Hydrogenation

  摘要：

  The new amido complex OsH(NHCMe2CMe2NH2)(PPh3)(2) (2) reacts with weak acids HX to give complexes OsHX(tmen)(PPh3)(26) (1; X = Cl, 3; X = NCCHCN, and X = H; tmen = NH2CMe2CMe2NH2) and is an active ketone hydrogenation catalyst. HX is completely transferred from Os to Ru in the reactions of the amido complex RuH(NHCMe2CMe2NH2)(PPh3)(2) with complexes 1 and 3.

  DOI：

  10.1021/om048998k
• 作为产物：
  描述：

  丙二腈 、 OsH(NHCMe₂CMe₂NH₂)(PPh₃)₂ 以 not given 为溶剂， 生成 OsH(NCCHCN)(tmen)(triphenylphosphine)2
  参考文献：
  名称：

  Reactions of an Amido Hydrido Complex of Osmium, OsH(NHCMe₂CMe₂NH₂)(PPh₃)₂:  HX Addition, HX Transfer, and Ketone H₂ Hydrogenation

  摘要：

  The new amido complex OsH(NHCMe2CMe2NH2)(PPh3)(2) (2) reacts with weak acids HX to give complexes OsHX(tmen)(PPh3)(26) (1; X = Cl, 3; X = NCCHCN, and X = H; tmen = NH2CMe2CMe2NH2) and is an active ketone hydrogenation catalyst. HX is completely transferred from Os to Ru in the reactions of the amido complex RuH(NHCMe2CMe2NH2)(PPh3)(2) with complexes 1 and 3.

  DOI：

  10.1021/om048998k