(E)-2,2'-diethoxy-6,6'-bis[2-(pinacolboryl)vinyl]-1,1'-binaphthalene | 779357-35-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (E)-2,2'-diethoxy-6,6'-bis[2-(pinacolboryl)vinyl]-1,1'-binaphthalene
• 英文别名: 2-[(E)-2-[6-ethoxy-5-[2-ethoxy-6-[(E)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethenyl]naphthalen-1-yl]naphthalen-2-yl]ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS: 779357-35-6
• 化学式: C₄₀H₄₈B₂O₆
• 分子量: 646.44
• InChiKey: XDVDGMPLFXCBQM-MBALSZOMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.75
• 重原子数：
  48
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  频那醇硼烷 、 (R)-2,2'-diethoxy-6,6'-diethynyl-1,1'-binaphthalene 在 三乙胺 作用下， 以 环己烷 为溶剂， 以74%的产率得到(E)-2,2'-diethoxy-6,6'-bis[2-(pinacolboryl)vinyl]-1,1'-binaphthalene
  参考文献：
  名称：

  Stereoselective Hydroboration of Diynes and Triyne to Give Products Containing Multiple Vinylene Bridges:  A Versatile Application to Fluorescent Dyes and Light-Emitting Copolymers

  摘要：

  The Rh(I)-catalyzed hydroboration of a variety of aromatic diynes and a triyne afforded bis(boryl)- and tris(boryl)vinyl products. The hydroboration products under-went Suzuki cross-coupling reactions with a variety of substrates containing chromophore units to give fluorescent dye-substituted products. The hydroboration product also reacted with dibromoarenes to afford an oligomer with a vinylene unit along the oligomer backbone.

  DOI：

  10.1021/om049832m

文献信息

• Stereoselective Hydroboration of Diynes and Triyne to Give Products Containing Multiple Vinylene Bridges:  A Versatile Application to Fluorescent Dyes and Light-Emitting Copolymers
  作者：Taegweon Lee、Chul Baik、Il Jung、Kyu Ho Song、Sanghoon Kim、Duckhyun Kim、Sang Ook Kang、Jaejung Ko

  DOI：10.1021/om049832m

  日期：2004.9.1

  The Rh(I)-catalyzed hydroboration of a variety of aromatic diynes and a triyne afforded bis(boryl)- and tris(boryl)vinyl products. The hydroboration products under-went Suzuki cross-coupling reactions with a variety of substrates containing chromophore units to give fluorescent dye-substituted products. The hydroboration product also reacted with dibromoarenes to afford an oligomer with a vinylene unit along the oligomer backbone.