di(9-anthryl)dimethylsilane | 99192-71-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: di(9-anthryl)dimethylsilane
• 英文别名: Bis(9-anthryl)dimeth-ylsilane；di(anthracen-9-yl)-dimethylsilane
• CAS: 99192-71-9
• 化学式: C₃₀H₂₄Si
• 分子量: 412.606
• InChiKey: HZRXJNJIKWBSPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.12
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  di(9-anthryl)dimethylsilane 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 氯仿 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Sakurai, Hideki, Phosphorus and Sulfur and the Related Elements, 1986, vol. 27, p. 205 - 210

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(9,10-dihydroanthracen-9-yl)-dimethylsilane 在 正丁基锂 、 四甲基乙二胺 、 cadmium(II) chloride 作用下， 生成 di(9-anthryl)dimethylsilane
  参考文献：
  名称：

  Daney, M.; Vanucci, C.; Desvergne, J-P., Tetrahedron Letters, 1985, vol. 26, # 12, p. 1505 - 1508

  摘要：

  DOI：

文献信息

• PHOTOCHEMISTRY OF DI(9-ANTHRYL)DIMETHYLSILANE AND -GERMANE
  作者：Hideki Sakurai、Kenkichi Sakamoto、Akihiro Nakamura、Mitsuo Kira

  DOI：10.1246/cl.1985.497

  日期：1985.4.5

  By irradiation, both di(9-anthryl)dimethylsilane and -germane afforded a new type of [4+2] intramolecular addition products that underwent quantitative cycloreversion by thermolysis. The photoproduct from the former was converted to a novel naphthotriptycene derivative.

  通过辐照，二(9-蒽基)二甲基硅烷和-锗烷都产生了一种新型的[4+2]分子内加成产物，并通过热分解进行定量环化。前者的光反应产物被转化为一种新型萘三联苯衍生物。
• Karatsu, Takashi; Shibata, Toshifumi; Nishigaki, Atsuko, Chemistry Letters, 2001, # 10, p. 994 - 995
  作者：Karatsu, Takashi、Shibata, Toshifumi、Nishigaki, Atsuko、Fukui, Keijiro、Kitamura, Akihide

  DOI：——

  日期：——
• π−π and σ−π Interactions in α,ω-Di-(9-anthryl) and Di-(1-naphthyl) Oligosilanes Studied by Time-Resolved Fluorescence in Solution
  作者：Takashi Karatsu、Toshifumi Shibata、Atsuko Nishigaki、Akihide Kitamura、Yusuke Hatanaka、Yoshinobu Nishimura、Shin-ichiro Sato、Iwao Yamazaki

  DOI：10.1021/jp0355760

  日期：2003.11.1

  The photophysical properties of two series of oligosilanes, (1-naphthyl)-(SiMe2)(n)-(1-naphthyl) (1-5) and (9-anthryl)-(SiMe2)(n)-(9-anthryl) (6-10) with n = 1-4 and 6, were investigated. In these compounds, two types of interactions, a pi-pi interaction between two aromatic groups and a sigma-pi interaction between aromatics and: a silicon chain unit, were observed. Intramolecular excimer emission was observed in cyclohexane when n greater than or equal to 2. The strongest excimer emission of 2 and 7 is different from the Hirayama rule (n = 3) proposed for carbon analogues and also shows that intramolecular cycloaddition is minor. The time-resolved fluorescence speptra of an anthryl series revealed that the time constant of excimer formation varied depending on the chain length (82-152 ps). In the cases of 4, 5, and 10, charge-transfer (CT) emission was observed in acetonitrile or THF. The time constant of the CT-state formation for 10 was relatively slow (45 ps), which may indicate a conformational change. Monomer emission from the locally excited state was observed for I and 6 in both cyclohexane and acetonitrile.
• ——
  作者：SAKURAI XIDEHKI、 KIRA MITSUO、 SAKAMOTO KEHNKITI

  DOI：——

  日期：——