Herrmann, Wolfgang A,; Thiel, Werner R.; Herdtweck, Eberhartd, Chemische Berichte, 1990, vol. 123, # 2, p. 271 - 276
作者:Herrmann, Wolfgang A,、Thiel, Werner R.、Herdtweck, Eberhartd
DOI:——
日期:——
Herrmann, Wolfgang A.; Kuehn, Fritz E.; Romao, Carlos C., Chemische Berichte, 1994, vol. 127, # 1, p. 47 - 54
作者:Herrmann, Wolfgang A.、Kuehn, Fritz E.、Romao, Carlos C.、Kleine, Matthias、Mink, Janos
DOI:——
日期:——
Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R<sub>3</sub>tach)ReO<sub>3</sub>]<sup>+</sup> (R = −CH<sub>3</sub>, −CH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>) and Its Substitution Reactions
作者:Henrik Braband、Sebastian Imstepf、Michael Felber、Bernhard Spingler、Roger Alberto
DOI:10.1021/ic902114p
日期:2010.2.15
N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the [(R(3)tach)ReO3](+) type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the [ReO3](+) motif for Re-VII complexes.