| 479195-42-1

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• CAS: 479195-42-1
• 化学式: C₂H₂Xe₂
• 分子量: 288.618
• InChiKey: RIBDLAACYDXQGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.53
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氙气 、 乙炔 以 solid matrix 为溶剂， 生成 氙二氢化物 、 、 Ethynyl(hydrido)xenon 、 、 C2*xenon complex
  参考文献：
  名称：

  Fluorine-Free Organoxenon Chemistry:  HXeCCH, HXeCC, and HXeCCXeH

  摘要：

  Three novel Xe-containing organic compounds, HXeCCH, HXeCC (open-shell species), and HXeCCXeH, are identified using infrared absorption spectroscopy. They are prepared in a low-temperature Xe matrix using UV photolysis of acetylene and subsequent annealing at 40-45 K. The experimental observations are supported by extensive ab initio calculations. This work demonstrates a new way to activate the H-Ctbd1;C- group without use of XeF(2), which can extend the range of organoxenon compounds.

  DOI：

  10.1021/ja034485d

文献信息

• Fluorine-Free Organoxenon Chemistry:  HXeCCH, HXeCC, and HXeCCXeH
  作者：Leonid Khriachtchev、Hanna Tanskanen、Jan Lundell、Mika Pettersson、Harri Kiljunen、Markku Räsänen

  DOI：10.1021/ja034485d

  日期：2003.4.1

  Three novel Xe-containing organic compounds, HXeCCH, HXeCC (open-shell species), and HXeCCXeH, are identified using infrared absorption spectroscopy. They are prepared in a low-temperature Xe matrix using UV photolysis of acetylene and subsequent annealing at 40-45 K. The experimental observations are supported by extensive ab initio calculations. This work demonstrates a new way to activate the H-Ctbd1;C- group without use of XeF(2), which can extend the range of organoxenon compounds.