22,28,34,39-Tetratert-butyl-43,44-dihydroxy-3,9,12,18-tetraoxa-6,15-diazahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1,19,21,23,26(44),27,29,32,34,37,39,41(43)-dodecaene-5,16-dione | 136158-06-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 22,28,34,39-Tetratert-butyl-43,44-dihydroxy-3,9,12,18-tetraoxa-6,15-diazahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1,19,21,23,26(44),27,29,32,34,37,39,41(43)-dodecaene-5,16-dione
• 英文别名: 22,28,34,39-tetratert-butyl-43,44-dihydroxy-3,9,12,18-tetraoxa-6,15-diazahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1,19,21,23,26(44),27,29,32,34,37,39,41(43)-dodecaene-5,16-dione
• CAS: 136158-06-0
• 化学式: C₅₄H₇₂N₂O₈
• 分子量: 877.174
• InChiKey: VQPRHTNNDLFLPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  64
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  136
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  5,11,17,23-tetra-tert-butyl-25,27-di(ethoxycarbonylmethoxy)-26,28-dihydroxycalix[4]arene 在 对甲苯磺酸一水合物 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 252.0h， 生成 22,28,34,39-Tetratert-butyl-43,44-dihydroxy-3,9,12,18-tetraoxa-6,15-diazahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1,19,21,23,26(44),27,29,32,34,37,39,41(43)-dodecaene-5,16-dione
  参考文献：
  名称：

  Ostaszewski, Ryszard; Stevens, Tieme W.; Verboom, Willem, Recueil des Travaux Chimiques des Pays-Bas, 1991, vol. 110, # 6, p. 294 - 298

  摘要：

  DOI：

文献信息

• Synthesis and dichromate anion extraction ability of p-tert-butylcalix[4]arene diamide derivatives with different binding sites
  作者：Aydan Yilmaz、Begum Tabakci、Ezgi Akceylan、Mustafa Yilmaz

  DOI：10.1016/j.tet.2007.03.138

  日期：2007.6

  The article describes the synthesis and evaluation of the dichromate anion (Cr2O72-/HCr2O7-) extraction properties of p-tert- butylcalix[4]arene diamide derivatives (5-7) containing different binding sites. Among these compounds, 6 and 7 have been synthesized via aminolysis in a toluene-methanol solvent system with 3-aminomethylpyridine and 3,6-dioxa-1,8-diamino octane, respectively. On the other hand, compound 5 has been synthesized via an acid chloride method due to its inefficiency under aminolysis. The extraction properties of these diamides toward dichromate anions are studied by liquid-liquid extraction. The results show that p-tert-butylcalix[4]arene diamide derivative 7 exhibited a much higher affinity toward dichromate anions than that of 6 due to its special structure, while 5 was an ineffective ligand for these anions. (c) 2007 Elsevier Ltd. All rights reserved.
• Boehmer, Volker; Ferguson, George; Gallagher, John F., Journal of the Chemical Society. Perkin transactions I, 1993, # 13, p. 1521 - 1527
  作者：Boehmer, Volker、Ferguson, George、Gallagher, John F.、Lough, Alan J.、McKervey, M. Anthony、et al.

  DOI：——

  日期：——
• Ostaszewski, Ryszard; Stevens, Tieme W.; Verboom, Willem, Recueil des Travaux Chimiques des Pays-Bas, 1991, vol. 110, # 6, p. 294 - 298
  作者：Ostaszewski, Ryszard、Stevens, Tieme W.、Verboom, Willem、Reinhoudt, David N.、Kaspersen, Frans M.

  DOI：——

  日期：——