2-isopropoxy-6-methyl-benzenesulphonyl chloride | 187471-22-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-isopropoxy-6-methyl-benzenesulphonyl chloride
• 英文别名: 2-Methyl-6-propan-2-yloxybenzenesulfonyl chloride
• CAS: 187471-22-3
• 化学式: C₁₀H₁₃ClO₃S
• mdl: MFCD19201193
• 分子量: 248.73
• InChiKey: AAMDRHUKJGBCEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-isopropoxy-6-methyl-benzenesulphonyl chloride 以 ammonium hydroxide 为溶剂， 生成 2-isopropoxy-6-methyl-benzenesulphonamide
  参考文献：
  名称：

  Substituted aryl sulphonyl (thio) ureas as herbicides

  摘要：

  该发明涉及新的取代芳基磺酰（硫）脲，其中：A为氮或CH基团，Q为氧或硫，R1为氢，卤素或可选取代的烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，环烷基，环烷氧基或杂环氧基，R2为氢，卤素或可选取代的烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，环烷基，环烷氧基或杂环氧基，R3为氢或可选取代的烷基，R4为可选取代的烷基，烷氧基，烯基，炔基，烯氧基，炔氧基，环烷基，环烷氧基或环烷基烷基，R5为氢，甲酰基或可选取代的烷基，烷基羰基，烷氧基羰基，烷基磺酰，烯基，炔基，环烷基，环烷基羰基，环烷基磺酰或杂环基，以及公式（I）化合物的盐，但不包括化合物N-（4,6-二甲基嘧啶-2-基）-N'-[2-（1,1,2,2-四氟乙氧基）-6-甲基苯磺酰]-脲。

  公开号：

  US06451737B1

文献信息

• Substituted aryl sulphonyl(thio)ureas
  申请人：——

  公开号：US20030153463A1

  公开（公告）日：2003-08-14

  The invention relates to novel substituted arylsulphonyl(thio)ureas 1 in which A represents nitrogen or a CH grouping, Q represents oxygen or sulphur, R 1 represents hydrogen, halogen or respectively optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or heterocyclyloxy, R 2 represents hydrogen, halogen or respectively optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or heterocyclyloxy, R 3 represents hydrogen or optionally substituted alkyl, R 4 represents respectively optionally substituted alkyl, alkoxy, alkenyl, alkinyl, alkenyloxy, alkinyloxy, cycloalkyl, cycloalkyloxy or cycloalkylalkyl, and R 5 represents hydrogen, formyl or respectively optionally substituted alkyl, alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, alkenyl, alkinyl, cycloalkyl, cycloalkylcarbonyl, cycloalkylsulphonyl or heterocyclyl, and to salts of compounds of the formula (I), except for the compound N-(4,6-dimethyl-pyrimidin-2-yl)-N′-[2-(1,1,2,2-tetrafluoro-ethoxy)-6-methyl-phenylsulphonyl]-urea, to processes for preparing the novel compounds and to their use as herbicides.

  本发明涉及新型取代的芳基磺酰基（硫代）脲类化合物 1 其中 A 代表氮或 CH 基团、 Q 代表氧或硫、 R 1 分别代表氢、卤素或任选取代的烷基、烷氧基、烷硫基、烷基氨基、二烷基氨基、环烷基、环烷氧基或杂环氧基、 R 2 分别代表氢、卤素或任选取代的烷基、烷氧基、烷硫基、烷基氨基、二烷基氨基、环烷基、环烷氧基或杂环氧基、 R 3 代表氢或任选取代的烷基、 R 4 分别代表任选取代的烷基、烷氧基、烯基、炔基、烯氧基、炔氧基、环烷基、环烷氧基或环烷基烷基，以及 R 5 分别代表氢、甲酰基或任选取代的烷基、烷基羰基、烷氧基羰基、烷基磺酰基、烯基、炔基、环烷基、环烷基羰基、环烷基磺酰基或杂环基、 以及式 (I) 化合物的盐、 化合物 N-(4,6-二甲基嘧啶-2-基)-N′-[2-(1,1,2,2-四氟-乙氧基)-6-甲基苯基磺酰基]-脲除外、 新型化合物的制备工艺及其作为除草剂的用途。
• Substituted aryl sulphonyl(thio)ureas used as herbicides
  申请人：Gesing Rudolf F. Ernst

  公开号：US20050004123A1

  公开（公告）日：2005-01-06

  The invention relates to novel substituted arylsulphonyl(thio)ureas in which A represents nitrogen or a CH grouping, Q represents oxygen or sulphur, R 1 represents hydrogen, halogen or respectively optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or heterocyclyloxy, R 2 represents hydrogen, halogen or respectively optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or heterocyclyloxy, R 3 represents hydrogen or optionally substituted alkyl, R 4 represents respectively optionally substituted alkyl, alkoxy, alkenyl, alkinyl, alkenyloxy, alkinyloxy, cycloalkyl, cycloalkyloxy or cycloalkylalkyl, and R 5 represents hydrogen, formyl or respectively optionally substituted alkyl, alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, alkenyl, alkinyl, cycloalkyl, cycloalkylcarbonyl, cycloalkylsulphonyl or heterocyclyl, and to salts of compounds of the formula (I), except for the compound N-( 4,6 -dimethyl-pyrimidin- 2 -yl)-N′-[ 2 -( 1,1,2,2 -tetrafluoro-ethoxy)- 6 -methyl-phenylsulphonyl]-urea, to processes for preparing the novel compounds and to their use as herbicides.
• US6251831B1
  申请人：——

  公开号：US6251831B1

  公开（公告）日：2001-06-26
• US6451737B1
  申请人：——

  公开号：US6451737B1

  公开（公告）日：2002-09-17
• US6525211B1
  申请人：——

  公开号：US6525211B1

  公开（公告）日：2003-02-25