[(3,4-dimethoxy-N-methyl-N-phenylbenzamide)Pd(μ-trifluoroacetate)]2 | 1300078-99-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [(3,4-dimethoxy-N-methyl-N-phenylbenzamide)Pd(μ-trifluoroacetate)]2
• CAS: 1300078-99-2
• 化学式: C₃₆H₃₂F₆N₂O₁₀Pd₂
• 分子量: 979.488
• InChiKey: QALBGOSNANNRFJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,4-dimethoxy-N-methyl-N-phenylbenzamide 、 palladium diacetate 、 三氟乙酸 以 1,2-二氯乙烷 为溶剂， 以47%的产率得到[(3,4-dimethoxy-N-methyl-N-phenylbenzamide)Pd(μ-trifluoroacetate)]2
  参考文献：
  名称：

  Cyclopalladation of N-phenylbenzamides: Synthesis and structure of bimetallic palladium(II)-complexes

  摘要：

  Three bimetallic palladium(II) complexes were generated by cyclopalladation of N-methyl-N-phenylbenzamide derivatives, substrates known to undergo oxidative intramolecular cross-coupling via palladium catalysis. These isolable Pd-complexes were characterized by X-ray crystallography. Stoichiometric and catalytic experiments with [(3-methoxy-N-methyl-N-phenylbenzamide)Pd(mu-TFA)](2) were investigated, and this palladium complex was found to be an effective precatalyst for oxidative cross-coupling. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.059