2,15-dithia[3,3](1,5)anthracenophane | 144344-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,15-dithia[3,3](1,5)anthracenophane
• 英文别名: dithia(1,5)<3.3>anthracenophane；dithia-1,5[3,3]-anthracenophane；3,18-Dithiaheptacyclo[22.6.2.29,12.05,10.020,25.027,31.016,33]tetratriaconta-1(30),5,7,9,11,13,15,20,22,24,26,28,31,33-tetradecaene；3,18-dithiaheptacyclo[22.6.2.29,12.05,10.020,25.027,31.016,33]tetratriaconta-1(30),5,7,9,11,13,15,20,22,24,26,28,31,33-tetradecaene
• CAS: 144344-00-3
• 化学式: C₃₂H₂₄S₂
• 分子量: 472.675
• InChiKey: UNMCWWLADDZHMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二甲基蒽-1,5-二羧酸酯 在 sodium sulfide 、 lithium aluminium tetrahydride 、 三溴化磷 作用下， 以 四氢呋喃 、 乙醇 、 苯 为溶剂， 生成 2,15-dithia[3,3](1,5)anthracenophane
  参考文献：
  名称：

  二噻蒽中的振荡激发转移：溶液中相干光化学过程中的量子跳动

  摘要：

  通过用飞秒上转换方法探测荧光各向异性衰减，研究了 THF 溶液中二噻蒽 (DTA) 的分子内电子激发转移。在 DTA 中，已知两个蒽环平行堆叠，但方向几乎正交。出现了表观周期为 1.2 ± 0.2 ps 和阻尼时间常数为 1.0 ± 0.1 ps 的阻尼振荡。根据 Wynne 和 Hochstrasser (Wynne, K.; Hochstrasser, RMJ Raman Spectrosc. 1995, 26, 561 ）。偶极-偶极能量转移相互作用的幅度估计为 40 cm-1，这与从振荡周期推导出的实验值 (29 cm-1) 符合可接受的协议。与朱等人报道的类似 2,2'-联萘 (BN) 病例相比。(Zhu, F.; Galli, C.; Hochstra...

  DOI：

  10.1021/jp012455w

文献信息

• Oscillatory Excitation Transfer in Dithiaanthracenophane: Quantum Beat in a Coherent Photochemical Process in Solution
  作者：Iwao Yamazaki、Seiji Akimoto、Tomoko Yamazaki、Shin-ichiro Sato、Yoshiteru Sakata

  DOI：10.1021/jp012455w

  日期：2002.3.1

  (DTA) in THF solution has been investigated by probing the fluorescence anisotropy decay with a femtosecond up-conversion method. In DTA, two anthracene rings are known to be stacked parallel, but with nearly orthogonal orientation. There appeared a damped oscillation of an apparent period of 1.2 ± 0.2 ps and a damping time constant of 1.0 ± 0.1 ps. It has been found that the oscillatory behavior is

  通过用飞秒上转换方法探测荧光各向异性衰减，研究了 THF 溶液中二噻蒽 (DTA) 的分子内电子激发转移。在 DTA 中，已知两个蒽环平行堆叠，但方向几乎正交。出现了表观周期为 1.2 ± 0.2 ps 和阻尼时间常数为 1.0 ± 0.1 ps 的阻尼振荡。根据 Wynne 和 Hochstrasser (Wynne, K.; Hochstrasser, RMJ Raman Spectrosc. 1995, 26, 561 ）。偶极-偶极能量转移相互作用的幅度估计为 40 cm-1，这与从振荡周期推导出的实验值 (29 cm-1) 符合可接受的协议。与朱等人报道的类似 2,2'-联萘 (BN) 病例相比。(Zhu, F.; Galli, C.; Hochstra...
• Synthesis of dithia(1,5)[3.3]anthracenophane with crossed structure and its excimer emission
  作者：Yoshiteru Sakata、Toshihiro Toyoda、Soichi Misumi、Tomoko Yamazaki、Iwao Yamazaki

  DOI：10.1016/s0040-4039(00)61194-2

  日期：1992.8

  The title compound 1 has been synthesized. X-ray analysis revealed that the two anthracene rings in 1 are stacked in parallel with a crossed orientation. In spite of such unusual structure 1 showed excimer emission at room temperature.
• Coherent Control of Oscillatory Excitation Transfer in Dithia-1,5[3,3]anthracenophane by a Phase-Locked Femtosecond Pulse Pair
  作者：Shin-ichiro Sato、Yoshinobu Nishimura、Yoshiteru Sakata、Iwao Yamazaki

  DOI：10.1021/jp027452d

  日期：2003.11.1

  The intramolecular electronic excitation coherence created by the first femtosecond laser pulse in a linked-anthracene dimer, dithia-1,5[3,3]-anthracenophane (DTA), was enhanced or depreciated by the interference with the second femtosecond laser pulse, which is phase-locked to the first pulse. Two anthracene rings in DTA are stacked parallel but with nearly orthogonal orientation. The interference intensity of fluorescence from DTA was measured as a function of delay time between two pulses with the optical phase angle being fixed with 0degrees (in-phase) or 180degrees (anti-phase). Two components of enhanced and depreciated oscillations appeared in the subpicosecond region as a function of the delay time, with the time periods depending on the excitation wavelength. On the basis of theoretical analysis, the two components were assigned to the sum and difference frequencies between the energy splitting of molecular eigenstates and the detuning of the laser frequency relative to the molecular electronic transition energy. The exciton splitting between the two superposition states of the local excitation was derived to be 2beta = 35 cm(-1), which is in close agreement with our previous result (29 cm(-1)) obtained from fluorescence anisotropy decay measurement.