1-[4-(4-Fluoranthen-3-ylphenyl)phenyl]-2-phenylbenzimidazole | 1315565-70-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-[4-(4-Fluoranthen-3-ylphenyl)phenyl]-2-phenylbenzimidazole
• CAS: 1315565-70-8
• 化学式: C₄₁H₂₆N₂
• 分子量: 546.671
• InChiKey: MXOQXZJFCCHJCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  43
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Kawamura Yuichiro

  公开号：US20120153268A1

  公开（公告）日：2012-06-21

  An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “E T b >E T h ” (where, E T h is the triplet energy of the host material, and E T b is the triplet energy of the barrier material).

  一种有机电致发光器件包括阳极、发光层、电子传输区和阴极，阳极、发光层、电子传输区和阴极依次堆叠，发光层包括主体材料和发射荧光的掺杂材料，其主峰波长为550nm或更低，电子传输区包括邻近发光层的阻挡层，该阻挡层包括具有电子传输结构部分和包括融合的多环芳香族碳化合物的三重态阻挡结构部分的阻挡材料，并满足“ETb>ETh”的关系（其中，ETh是主体材料的三重态能量，而ETb是阻挡材料的三重态能量）。
• NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Kawamura Masahiro

  公开号：US20120132899A1

  公开（公告）日：2012-05-31

  A nitrogen-containing heterocyclic derivative represented by the following formula (1): wherein any “12-a” groups of R 1 to R 12 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; any “a” groups of R 1 to R 12 are independently a single bond which is bonded to L 1 ; L 1 is a single bond, a “b+1” valent substituted or unsubstituted hydrocarbon ring group having 6 to 30 ring carbon atoms or a “b+1” valent substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; HAr is a substituted or unsubstituted nitrogen-containing heterocyclic group; and “a” and “b” are independently an integer of 1 to 4, and at least one of “a” and “b” is 1. Also disclosed is a nitrogen-containing heterocyclic derivative represented by the following formula (21) or (31):

  一种含氮杂环衍生物，由以下公式（1）表示：其中R1至R12中的任何“12-a”基团独立地是氢原子、氟原子、具有6至30个环碳原子的取代或未取代芳基基团或具有5至30个环原子的取代或未取代杂环基团；R1至R12中的任何“a”基团独立地是与L1相结合的单键；L1是单键、具有6至30个环碳原子的“b+1”价取代或未取代的碳氢环基团或具有5至30个环原子的“b+1”价取代或未取代的杂环基团；HAr是取代或未取代的含氮杂环基团；“a”和“b”分别是1至4的整数，且至少有一个“a”和“b”为1。还公开了一种由以下公式（21）或（31）表示的含氮杂环衍生物：
• NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP3192789A1

  公开（公告）日：2017-07-19

  A nitrogen-containing heterocyclic derivative represented by the following formula (31): wherein R401 to R416 are independently a hydrogen atom, a fluorine atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 30 carbon atoms, a substituted or unsubstituted arylsilyl group having 8 to 30 ring carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 20 ring carbon atoms, a substituted or unsubstituted alkylamino group, a substituted or unsubstituted arylamino group, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms; one of R401 to R410 and one of R411 to R416 are a single bond and is bonded to L1; L1 is a single bond, a substituted or unsubstituted "c+d" valent hydrocarbon group having 6 to 30 ring carbon atoms or a "c+d" valent heterocyclic group having 5 to 30 ring atoms; If each of substituents of R401 to R416 and L1 has a further substituent, the further substituent is an alkyl group, an alkylsilyl group, a halogenated alkyl group, a phenyl group, a naphthyl group, a phenanthryl group, a biphenyl group, a terphenyl group, a chryseny group, a benzophenanthryl group, a benzanthryl group, a benzochrysenyl group, a fluorenyl group, a fluoranthenyl group, a cycloalkyl group, an alkoxy group, a heterocyclic group, an aralkyl group, an aryloxy group, an arylthio group, an alkoxycarbonyl group, a halogen atom, a hydroxyl group, a nitro group, a cyano group, a carboxyl group, a dibenzofuranyl group, or a fluorenyl group; and "c" and "d" are independently an integer of 1 to 3; provided that L1, and R401 to R416 are not an anthracene containing group.

  下式(31)所代表的含氮杂环衍生物： 其中 R401 至 R416 独立地为氢原子、氟原子、具有 1 至 10 个碳原子的取代或未取代的烷基、具有 3 至 10 个碳原子的取代或未取代的环烷基、具有 3 至 30 个碳原子的取代或未取代的烷基硅基、具有 8 至 30 个环碳原子的取代或未取代的芳基硅基、具有 1 至 20 个环碳原子的取代或未取代的烷氧基、具有 6 至 20 个环碳原子的取代或未取代的芳氧基、取代或未取代的烷基氨基、取代或未取代的芳基氨基、具有 6 至 30 个环碳原子的取代或未取代的芳基或具有 5 至 30 个环原子的取代或未取代的杂环基团；R401 至 R410 中的一个和 R411 至 R416 中的一个是单键并与 L1 键合； L1 是单键、具有 6 至 30 个环碳原子的取代或未取代的 "c+d "价烃基或具有 5 至 30 个环原子的 "c+d "价杂环基； 如果 R401 至 R416 的每个取代基和 L1 具有另一取代基，则该另一取代基为烷基、烷基硅基、卤代烷基、苯基、萘基、菲基、联苯基、三联苯基、胆蒽基、苯并菲基、苯并蒽基苯并芘基、芴基、荧光苯基、环烷基、烷氧基、杂环基、芳基、芳氧基、芳硫基、烷氧羰基、卤素原子、羟基、硝基、氰基、羧基、二苯并呋喃基或芴基；和 c "和 "d "独立地为 1 至 3 的整数；条件是 L1 和 R401 至 R416 不是含蒽的基团。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2525425B1

  公开（公告）日：2014-10-15
• US8803420B2
  申请人：——

  公开号：US8803420B2

  公开（公告）日：2014-08-12