N-ethylphenylaminoxyl | 6146-30-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-ethylphenylaminoxyl
• 英文别名: Aethyl-phenyl-aminoxyl；N-Ethyl-phenyl-nitroxid；Aethyl-phenyl-aminoxid；N-Ethyl-N-phenyl-nitroxid
• CAS: 6146-30-1
• 化学式: C₈H₁₀NO
• 分子量: 136.173
• InChiKey: VDQHPMOEVIZWAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  4.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,3,2-Benzodioxaphosphol-2-amine, N-ethyl-N-phenyl- 在 叔丁基过氧化氢 作用下， 以 苯 为溶剂， 生成 N-ethylphenylaminoxyl
  参考文献：
  名称：

  Tkac, Alexander; Rueger, Claus; Schwetlick, Klaus, Collection of Czechoslovak Chemical Communications, 1980, vol. 45, # 4, p. 1182 - 1196

  摘要：

  DOI：

文献信息

• Radical transformations of some N-alkylanilines by their oxidation with different agents: an EPR study
  作者：Lenka Šafaříková、Ladislav Omelka、Petr Majzlík、Jan Světlík

  DOI：10.1007/s00706-012-0874-6

  日期：2013.2

  N-Alkylanilines X-NH-Ph (Ph = substituted phenyl ring) with two different types of alkyl substituent X [X = C2H5-CO-CH2CH(Ph), X = CH3, C2H5, CH(CH3)(2), CH2C6H5] were oxidized using different agents. While oxidation with 3-chloroperbenzoic acid leads to production of the corresponding aminoxyl radicals X-NOaEuro cent-Ph, it was confirmed that application of PbO2 resulted in the formation of aminyl radicals X-N-aEuro cent-Ph, as indirectly proved by the spin-trapping method. Contrary to those transformations, with employment of either Pb(OAc)(4) or t-BuO (2) (aEuro cent) radical, reactions taking place on the alkyl substituent were also observed.
• Tkac, Alexander; Rueger, Claus; Schwetlick, Klaus, Collection of Czechoslovak Chemical Communications, 1980, vol. 45, # 4, p. 1182 - 1196
  作者：Tkac, Alexander、Rueger, Claus、Schwetlick, Klaus

  DOI：——

  日期：——