| 1354630-44-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• CAS: 1354630-44-6
• 化学式: C₇₄H₄₃MgN₁₁
• 分子量: 1110.53
• InChiKey: AMLYEKGZJYCVGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,5-diphenylphthalonitrile 、 isoindolo[5,6-f]isoindole-1,3,6,8(2H,7H)tetraimine 在 magnesium acetate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 异戊醇 为溶剂， 反应 7.0h， 以19%的产率得到(bis(9(2),10(2),14(2),15(2),19(2),20(2)-hexaphenyltribenzo[g,l,q]-7,12,17,22-tetraazaporphyrino)-[b,g]naphthalene) dimagnesium
  参考文献：
  名称：

  Phenyl-substituted planar binuclear phthalo- and naphthalocyanines: synthesis and investigation of physicochemical properties

  摘要：

  Dodeca-phenyl-substituted planar binuclear phthalocyanine magnesium complexes with an extended pi-conjugation system were synthesized with high yields. Two approaches to the extension of the pi-system were presented: extension of an aromatic bridge or a peripheral pi-system. A maximum of near-IR absorption at 972 nm was observed in the case of the planar binuclear naphthalocyanine sharing a common benzene ring. Binuclear phthalo- and naphthalocyanines were characterized by high resolution MALDI-TOF mass spectrometry, UV/Vis/NIR and H-1 NMR spectroscopy. DFT modeling of the structure and chemical shift GIAO calculations were made. The formation of nanoaggregates in a solid film was proven using AFM. The electrochemical properties of binuclear naphthalocyanine complexes were investigated for the first time. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.10.012